Revealing substrate−molecule vibronic coupling enhancement, especially photoinduced charge transfer (CT) process, is hugely important for understanding Surface-enhanced Raman spectroscopy (SERS) enhancement mechanism. In this work, oxygen atoms were extracted from...

Chemical etching CTP to create a rough surface that has high enhancement factors of SERS.

Selective breaking of β-O-4 bonds is a challenge for lignin depolymerization. Herein, boron (B) was utilized to construct superficial MoO and subsurface Al(IV)–O–BO2 interfacial sites of Mo/sepiolite (SEP), which acted as Lewis acid sites to promote β-O-4 bond cleavage of lignin. Characterizations and density functional theory (DFT) calculations showed that B could interact with the quadridentate Al(IV) atoms of SEP to generate Al(IV)–O–BO2 and did not affect the incipient MoO of Mo/SEP. The experimental results demonstrated that the B content altered the catalytic performance of Mo/SEP, and B–Mo/SEP achieved 99.3% lignin liquefaction and the highest selectivity of phenol (48.5%) and ethoxyphenol (27.4%) monomers. Combined with DFT simulation, the results confirmed that the antibonding orbital of MoO accepted electrons of alcohol oxygen, while the B bonding orbital in Al(IV)–O–B–O2 received electrons of benzyl oxygen, promoting the formation of C+ intermediates. Simultaneously, oxygen vacancies in SEP activated the ethanol medium to facilitate enol intermediate hydrogenation for phenolic compounds.