2D titanium carbide (Ti 3 C 2 T x ) MXene films, with their well-defined microstructures and chemical functionality, provide a macroscale use of nano-sized Ti 3 C 2 T x flakes. Ti 3 C 2 T x films have attractive physicochemical properties favorable for device design, such as high electrical conductivity (up to 20 000 S cm -1 ), impressive volumetric capacitance (1500 F cm -3 ), strong in-plane mechanical strength (up to 570 MPa), and a high degree of flexibility. Here, the appealing features of Ti 3 C 2 T x -based films enabled by the layer-to-layer arrangement of nanosheets are reviewed. We devote attention to the key strategies for actualizing desirable characteristics in Ti 3 C 2 T x -based functional films, such as high and tunable electrical conductivity, outstanding mechanical properties, enhanced oxidation-resistance and shelf life, hydrophilicity/hydrophobicity, adjustable porosity, and convenient processability. This review further discusses fundamental aspects and advances in the applications of Ti 3 C 2 T x -based films with a focus on illuminating the relationship between the structural features and the resulting performances for target applications. Finally, the challenges and opportunities in terms of future research, development, and applications of Ti 3 C 2 T x -based films are suggested. A comprehensive understanding of these competitive features and challenges shall provide guidelines and inspiration for the further development of Ti 3 C 2 T x -based functional films, and contribute to the advances in MXene technology.

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