A general and practical method to directly convert phenols into primary anilines with cheap and easy-to-handle hydrazine as the amine and hydride sources catalyzed by Pd/C.

In many heterogeneous catalysts,t he interaction of supported metal species with am atrix can alter the electronic and morphological properties of the metal and manipulate its catalytic properties.I II-nitride semiconductors have au nique ability to stabilizeu ltra-small ruthenium (Ru) clusters (ca. 0.8 nm) at ah igh loading density up to 5wt%.n -Type III-nitride nanowires decorated with Ru sub-nanoclusters offer controlled surface charge properties and exhibit superior UVand visible-light photocatalytic activity for ammonia synthesis at ambient temperature.Ametal/semiconductor interfacial Schottky junction with a0 .94 eV barrier height can greatly facilitate photogenerated electron transfer from III-nitrides to Ru, rendering Ru an electron sink that promotes N Nb ond cleavage,a nd therebya chieving low-temperature ammonia synthesis.

This tutorial review showcases the diversity & utility of organophosphorus molecules, focusing on P(v) structures. Their rich nomenclature, application & industrial synthesis will be highlighted within the context of sustainable chemistry.