We demonstrate that the supramolecular structure can be formed through the fibrous self-assembly of the polyfluorene-based polymer F8BT in liquid crystal (LC) 5CB. With the utility of alignment layer, the F8BT molecules can be aligned and formed oriented polymer network. We found that the presence of oriented polymer network makes twisted nematic LC exhibit excellent electro-optical properties (EO) of driving voltage reduction and EO bump peak elimination. The polyfluorene-based supramolecular structure provides the function of stabilizing LC molecules. We consider this functional selfassembled network has potential to apply in various devices for the ability of improving performance in operating property.
We present a simple and efficient way to improve the performance of the twisted nematic liquid crystal (LC) system by doping a small amount of n-alcohols. The LCs modified by n-hexanol demonstrates the optimum electro-optical properties of lower driving voltage and shorter response time. Our measurements indicate that the n-alcohols can be treated as surfactants to modify LCs for lowering zenithal anchoring energy relative to undoped LCs. Without the drawbacks of precipitation and aggregation that the nanoparticles could have, the method of doping n-alcohol liquids provides a more stable and reliable choice to apply in the various LC display systems.
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