A new approach to the measurement of x−y uniformity of the surface of a paper sheet is described. Scanning electron micrographs are taken of both the top and bottom surfaces of a paper sheet and image-analyzed. The images were converted to grayscale, and the standard deviation of the pixel brightness was called the “SEM roughness index” and calculated for each surface. Both commercial newsprint sheets and handsheets made with kraft, TMP, and recycled fibers were examined. Debonders and cationic polymers were added to some sheets. The addition of debonders increases the index on the top side of the sheet but decreases it on the bottom. This is caused by the movement of fines from the top to the bottom side. The addition of cationic polymers increases the SEM roughness index by increasing the degree of microfloc formation. Samples taken across a reel from a commercial paper machine tend to show a mirror image relationship between the top and bottom surfaces. The SEM roughness index is able to detect subtle changes in sheet structure caused by differences in the mode of addition of polymers used for retaining fines in the sheet.
We quantified the effects of wood density (chip specific gravity) and wood chemical composition (cellulose, hemicellulose, and lignin) on the kraft pulp yield of 13-year-old loblolly pine trees (Pinus taeda) grown as part of a genetic selection study. Both bleachable (kappa No. 30) and linerboard grade (kappa No. 100) pulps were made from 18 trees selected for combinations of wood specific gravity and cellulose:hemicellulose:lignin ratios. Statistical analysis indicated that digester pulp yield correlated significantly with wood xylan content and cellulose-to-lignin ratio but was not strongly correlated to wood specific gravity. Near infrared (NIR) spectra were collected from wood samples and correlated with the total kraft pulp yields. The analyses for both kappa No. 30 and kappa No. 100 pulps provided strong calibration statistics, suggesting that papermakers can use NIR spectroscopy to esti-mate the bleachable and linerboard grade pulp yields of P. taeda whole-tree samples.
Mutant loblolly pine trees that are partially deficient in cinnamyl alcohol dehydrogenase (CAD) have been studied as a possible new source of pulpwood. Young (4-and 6-year-old) partially CAD-deficient pine trees are -20% more easily delignified (pulping and bleaching) and provide similar pulp yields to that of similarly aged normal pines grown on the same plots. Bleached pulp from a 6year-old partially CAD-deficient pine tree displayed better strength properties than the same age normal pine tree; this probably reflects the milder pulping conditions needed in the case of the partially CAD-deficient tree. Studies also were conducted on a limited number of 14-year-old trees from a different genetic background. In contrast to the results with young trees, no real differences in ease of delignification, pulp yields, bleached pulp strength properties, and wood specific gravities were observed with the 14-year-old trees. There would likely be no penalty if partially CAD-deficient trees were used for lumber products. The rapid growth of partially CAD-deficient trees could make them a valuable pulpwood.
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