Pa.,' while both of the authors at separate visits to the locality have been able to collect a few specimens. The new species were found in a somewhat limited area, and it is especially interesting to note the minerals which are associated with them, for they are very unusual even for Franklin, N. J., and would seem to indicate that peculiar conditions prevailed during the period when these minerals were being formed. The associated minerals are as follows: Native lead{6 and ooppemL clinohedritej: roeblingite, § axinite in transparent yellow crystals, willemite in exceptionally fine, transparent green crystals, vesuvianite, datolite, barite, garnet, brownish-blaek phlogopite anda little franklinite. The presence of axinite and datolite containing boron and of phlogopite would seem to indicate that the minerals, part of them at least, have resulted from metamorphism brought about by the action of intruded igneous masses either during the pneumatolitic period When such masses were giving off heated aqueous vapors carrying boron and fluorine compounds, or during a period when heated waters, laden with mineralizing agents, were circulating through the deposit.
HANCOCKITE.This mineral was found in considerable quantity both massive and in cellular masses of a brownish-red or maroon color, and attention has already been called to it as a new species by Penfield and Foote in their description of clinohedrite." Thus
Versatile and flexible gas analysis for compositional identification and quantification is a demand found in a variety of diverse sectors. As such, a compact, deployable instrument exhibiting both high specificity and sensitivity is a highly attractive proposition for a wide range of applications. In this paper, we describe a gas phase Raman spectroscopy-based device using state-of-the-art anti-resonant (tubular) hollow core micro-structured optical fibre (HC-MOF).This fibre architecture allows the use of lengths that are typically longer than have been demonstrated previously, allowing substantially enhanced interaction lengths between the pump laser and the gas sample to be achieved, addressing the sensitivity challenges typically observed in gas-phase Raman measurements and enabling application for remote sensing in hazardous environments. We describe the successful development of a compact, fibreintegrated instrument and present results obtained during a test campaign at an industrial laboratory; marking a milestone in gas-phase Raman spectroscopy. The unique properties of the MOF used allowed a 20-m length to be utilised, representing a new record length for gas phase Raman measurements. The identification and quantification of a variety of gas species, ranging from simple homonuclear diatomic gases to heteronuclear organic gas species were achieved, and, building on previous studies, the instruments stability, gas concentration linearity response, and the hollow core fibre filling and purging characteristics were investigated.
K E Y W O R D Sfibre-enhanced gas Raman, hollow core anti-resonant tubular fibre, industrial application, multi-species detection
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