Drought is a complex natural hazard that may have destructive damages on societal properties and even lives. Generally, socioeconomic drought occurs when water resources systems cannot meet water demand, mainly due to a weather-related shortfall in water supply. This study aims to propose a new method, a heuristic method, and a new index, the socioeconomic drought index (SEDI), for identifying and evaluating socioeconomic drought events on different severity levels (i.e., slight, moderate, severe, and extreme) in the context of climate change. First, the minimum in-stream water requirement (MWR) is determined through synthetically evaluating the requirements of water quality, ecology, navigation, and water supply. Second, according to the monthly water deficit calculated as the monthly streamflow data minus the MWR, the drought month can be identified. Third, according to the cumulative water deficit calculated from the monthly water deficit, drought duration (i.e., the number of continuous drought months) and water shortage (i.e., the largest cumulative water deficit during the drought period) can be detected. Fourth, the SEDI value of each socioeconomic drought event can be calculated through integrating the impacts of water shortage and drought duration. To evaluate the applicability of the new method and new index, this study examines the drought events in the East River basin in South China, and the impact of a multi-year reservoir (i.e., the Xinfengjiang Reservoir) in this basin on drought analysis is also investigated. The historical and future streamflow of this basin is simulated using a hydrologic model, Variable Infiltration Capacity (VIC) model. For historical and future drought analysis, the proposed new method and index are feasible to identify socioeconomic drought events. The results show that a number of socioeconomic drought events (including some extreme ones) may occur in future, and the appropriate reservoir operation can significantly ease such situation.
The separation of ethyl acetate and ethanol (EtOH) is important but difficult due to their close boiling points and formation of an azeotropic mixture. The separation of the azeotropic mixture of ethyl acetate and EtOH using the hydrophilic ionic liquids (ILs) 1-alkyl-3-methylimidazolium chloride (alkyl = butyl, hexyl, and octyl) ([C n mim]Cl, n = 4, 6, 8) and 1-allyl-3-methylimidazolium chloride and bromide ([Amim]Cl and [Amim]Br) has been investigated. Triangle phase diagrams of five ILs with ethyl acetate and EtOH were constructed, and the biphasic regions were found as follows: [Amim]Cl > [Amim]Br > [C4mim]Cl > [C6mim]Cl > [C8mim]Cl. The mechanisms of the ILs including cation, anion, and polarity effect were discussed. The results showed that the hydrophilic ILs [C n mim]Cl (n = 4, 6, 8), [Amim]Br, and [Amim]Cl could remove EtOH effectively from the azeotropic mixture of ethyl acetate and EtOH. Moreover, it was found that [Amim]Cl had the highest extraction efficiency, and the purity of ethyl acetate could reach 99.27 wt % after extraction twice. These hydrophilic ILs are easily synthesized and purified, are economically feasible, and caused no erosion to the equipment, which usually happened for ILs containing F. ILs could be recycled by simple distillation. The separating process can reduce the energy consumption greatly, and the total process is green and environmentally benign.
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