A simple method has been developed to produce SERS-active metal surfaces. Six metal surfaces (cadmium, nickel, gold, iron, copper, and silver) have been prepared on an aluminum foil underlayment by chemical reduction and strong surface-enhanced Raman signals have been observed for pyridine species on these surfaces. This permits the direct comparison of pyridine spectra on different metal surfaces prepared by the same chemically clean method. The differences among the SER spectra of the aqueous pyridine species using different metals generally follow the trend of silver, cadmium, nickel, iron, gold, and copper, which can be explained by the selective formation of alpha-pyridyl species and the equilibria between end-on adsorbed pyridines and edge-on adsorbed alpha-pyridyl species on the different metal surfaces.

Wireless sensor network (WSN) is a kind of distributed and self-organizing networks, in which the sensor nodes have limited communication bandwidth, memory, and limited energy. The topology construction of this network is usually vulnerable when attacked by malicious nodes. Besides, excessive energy consumption is a problem that can not be ignored. Therefore, this paper proposes a secure topology protocol of WSN which is trust-aware and of low energy consumption, called TLES. The TLES considers the trust value as an important factor affecting the behavior of node. In detail, the TLES would take trust value, residual energy of the nodes, and node density into consideration when selecting cluster head nodes. Then, TLES constructs these cluster head nodes by choosing the next hop node according to distance to base station (BS), nodes’ degrees, and residual energy, so as to establish a safe, reliable, and energy saving network. Experimental results show that the algorithm can effectively isolate the malicious node in the network and reduce the consumption of energy of the whole network.