The green up-conversion emissions centered at the wavelengths of about 534nm and 549nm of the Er3+ doped silicate glass were recorded, using a 978 nm semiconductor laser diode (LD) as an excitation source. The fluorescence intensity ratio (FIR) of the green up-conversion emissions at about 534nm and 549nm in the Er3+ doped silicate glass was studied as a function of temperature over the temperature range of 296K-673K. The maximum sensitivity and the temperature resolution derived from the FIR of the green up-conversion emissions are approximately 0.0023K-1 and 0.8K, respectively. It is demonstrated that the prototype optical temperature sensor based on the FIR technique from the green up-conversion emissions in the Er3+ doped silicate glass could play a major role in temperature measurement.
Tm³⁺/Tb³⁺/Mn²⁺ tridoped phosphate glasses containing different Mn²⁺ ion concentrations were synthesized to explore new white-light-emitting material. Under 355 nm excitation, the CIE coordinates (x=0.328, y=0.337) of the Mn0.10 sample doped with 0.10 wt. % Mn²⁺ are close to the standard equal energy white-light illumination (x=0.333, y=0.333). The quantum efficiency of the Mn0.01 sample is very high (~72.32%). The concentration of Mn²⁺ ions has a great effect on the emission color, and the energy transitions from Tm³⁺, Tb³⁺ to Mn²⁺ become more intense with an increase in Mn2+ ion concentrations. The phenomenon is reasonably interpreted based on the analysis of the luminescence lifetime.
The optical properties of truncated triangular silver nanoprisms and their influences on the fluorescence of europium complex Eu(TTFA)(3) were investigated in theory and experiment separately. In theory, we found that the fluorescence of Eu ions would be greatly enhanced by these nanoprisms, the enhancement factor of the fluorescence depended on the concentrations of nanoprisms. They were verified in the experiment. The influence of silver nanoprisms on the radiative and nonradiative decay rates of Eu ions were also deduced, and found that the silver nanoprisms greatly reduced the energy loss caused by the nonradiative decay.
Sb3+/Mn2+ co-doped phosphate glasses were prepared by high temperature melting method. The absorption, excitation, and emission spectra of the glasses were investigated. The glasses are transparent in the visible light region and can emit strong red light under 275, 360, 415, or 520 nm excitation. Under 275 nm excitation, the emission colors of the glasses can vary from blue to red with the increasing of Mn2+ ion concentration. The materials will be helpful in developing glass greenhouse for the green plants.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.