An imidazole ester
skeleton (zeolitic imidazolate framework (ZIF))
was grown on the surface of a ZnAl-layered double hydroxide (ZnAl-LDH)
material to form a porous composite (ZIF-ZnAl-LDH). To understand
the adsorption characteristics of the two materials, the effects of
pH, adsorption time, and adsorption concentration on the adsorption
of Congo red (CR) solution were investigated comprehensively. In addition,
ZnAl-LDH and ZIF-ZnAl-LDH were characterized by Fourier transform
infrared (FTIR), X-ray diffraction (XRD), Brunauer–Emmett–Teller
(BET), and X-ray photoelectron spectroscopy (XPS). The results clearly
showed that ZnAl-LDH had a lamellar structure with a diameter of approximately
200–500 nm and ZIF-ZnAl-LDH had a regular three-dimensional
hexagonal structure. The kinetics and thermodynamics of the CR adsorption
by ZnAl-LDH and ZIF-ZnAl-LDH can be described using pseudo-second-order
(PSO) and Langmuir models, respectively. The highest value of adsorption
capacity obtained from the Langmuir equation was equal to 625.00 and
909.09 mg/g for these two compounds, respectively. The values of the
standard Gibbs free energy (ΔG°), entropy
(ΔS°), and enthalpy (ΔH°) obtained for these adsorption processes prove that the adsorption
of CR by ZnAl-LDH and ZIF-ZnAl-LDH is a spontaneous endothermic process.
Furthermore, through the analysis of the characterization results,
it is concluded that the adsorption mechanisms of ZnAl-LDH and ZIF-ZnAl-LDH
on CR are mainly dominated by electrostatic action, functional group
action, surface pore adsorption, and anion exchange.
Zn–Al layered
bimetallic composites were prepared by ethanol
strengthening and co-precipitation using banana straw as a raw material.
A high-efficiency phosphorus adsorbent (ZnAl-LDO-BC) was obtained
by calcination at a high temperature. The kinetics and thermodynamics
of phosphorus adsorption on ZnAl-LDO-BC were then studied. The results
showed that the adsorption process of ZnAl-LDO-BC corresponds with
the pseudo-second-order (PSO) kinetic equation and the Langmuir model.
The theoretical maximum adsorption capacity of ZnAl-LDO-BC is 111.11
mg/g (at 45 °C, 500 mg/L phosphorus initial concentration). The
influence of anions on phosphorus adsorption decreased in strength
in the following order: CO3
2– > SO4
2– > NO3
–.
Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS),
Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction
(XRD) were used to characterize the adsorption of phosphorus on ZnAl-LDO-BC
and showed that ZnAl-LDO-BC can efficiently adsorb phosphorus. The
adsorption mechanism utilizes both O–H and C–H on the
surface of ZnAl-LDO-BC for the adsorption of PO4
3–, forming Zn3(PO4)2·4H2O via complexation precipitation; additionally, biochar
surface adsorption and interlayer adsorption are indispensable forms
of phosphate adsorption. With the systematic study of phosphorus adsorption
by ZnAl-LDO-BC, a novel green technology was developed for addressing
phosphorus pollution.
Biochars were produced with magnesium chloride as an additive for the sorption of hexavalent chromium dissolved in water using five types of straw (from taro, corn, cassava, Chinese fir, and banana) and one type of shell (Camellia oleifera) as the raw materials. The removal of hexavalent chromium by the six biochars mainly occurred within 60 min and then gradually stabilized. The kinetics of the adsorption process were second order, the Langmuir model was followed, and the adsorption of Cr(VI) by the six biochars was characterized by Langmuir monolayer chemisorption on a heterogeneous surface. Banana straw biochar (BSB) had the best performance, which perhaps benefitted from its special structure and best adsorption effect on Cr(VI), and the theoretical adsorption capacity was calculated as 125.00 mg/g. For the mechanism analysis, Mg-loaded biochars were characterized before and after adsorption by Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), and scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS). The adsorption mechanism differed from the adsorption process of conventional magnetic biochar, and biochar interactions with Cr(VI) were controlled mainly by electrostatic attraction, complexation, and functional group bonding. In summary, the six Mg-loaded biochars exhibit great potential advantages in removing Cr(VI) from wastewater and have promising potential for practical use, especially BSB, which shows super-high adsorption performance.
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