The on-line feedback control of sliding friction of metallic tribopairs lubricated by adsorbed sodium dodecyl sulfate (SDS) films was demonstrated on a customized tribosystem, in which the external electric field applied on the tribopair was modulated in feedback according to the electrical contact resistance signal. When a positive voltage was applied, the adsorption of SDS anions on the surface of tribopair was enhanced so that the boundary film was stable. When the contact resistance increased to a pre-set threshold (e.g., 6~10 Ω), which indicated the formation of a relatively complete boundary film, the external voltage was switched off for saving energy. For an aqueous solution with 160 mM SDS as the lubricant, the coefficient of friction (COF) was decreased by 24% for the 316 L plate/304 steel ball under 804 MPa by modulating the applied potential of +3.5 V. For the propylene carbonate lubricant with 5 mM SDS, the COF was decreased by 39% for the Cu plate/304 steel ball under 499 MPa and 54% for the Cu plate/bearing steel ball under 520 MPa by modulating the applied potential of +20 V. This novel approach could be effective to keep good boundary lubrication of machine components under variable work conditions by on-line sensing and actuation.

We use molecular dynamics simulations to study the frictional response of monolayers of the anionic surfactant sodium dodecyl sulfate and hemicylindrical aggregates physisorbed on gold. Our simulations of a sliding spherical asperity reveal the following two friction regimes: at low loads, the films show Amonton's friction with a friction force that rises linearly with normal load, and at high loads, the friction force is independent of the load as long as no direct solid–solid contact occurs. The transition between these two regimes happens when a single molecular layer is confined in the gap between the sliding bodies. The friction force at high loads on a monolayer rises monotonically with film density and drops slightly with the transition to hemicylindrical aggregates. This monotonous increase of friction force is compatible with a traditional plowing model of sliding friction. At low loads, the friction coefficient reaches a minimum at the intermediate surface concentrations. We attribute this behavior to a competition between adhesive forces, repulsion of the compressed film, and the onset of plowing.

Surfactant solutions are widely used in industry, and their steady-state lubrication properties have been comprehensively explored, while the “dynamic process” between steady states attracts much less attention. In this study, the lubrication behaviors of sodium dodecyl sulfate (SDS) and sodium bis (2–ethylhexyl) sulfosuccinate (Aerosol–OT, AOT) solutions were comparatively and extensively discussed. Experimental results showed that the duration of the dynamic process of AOT solution lubrication was significantly shorter than that of SDS. The essence of the dynamic process was revealed from the aspects of the running-in of solid surfaces and the adsorption process of surfactant molecules. Unlike the general recognition that the friction force evolution mainly corresponds to the running-in of surfaces, this study indicated that the dynamic adsorption behavior of surfactant molecules mainly contributes to this process. Various experiments and analyses showed that the smaller steric hindrance and lower orientation speed of SDS molecules led to longer diffusion into the confined contact zone and a longer duration of friction force decrease. This work enhances our understanding of the dynamic friction process in water-based lubrication, which could also have important implications for oil-based lubrication and its industrial applications.

In water-based ultralow or super low friction experiments, a running-in period before achieving the ultralow or super low friction is necessary and important. However, the effect of the change in contact geometry has not been fully realised. In this paper, a series of running-in tests on a Si3N4 ball and a WC plate have been performed in glycerol-water mixtures with different concentrations. The shape of the wear scars and the chemical compositions of the worn surfaces were characterised in detail. A numerical EHD and mixed lubrication model was established to comprehensively analyze the effects of geometric profiles, surface roughness, and working / lubrication conditions on ultralow or super low sliding friction. The experiment and simulation results of the study have provided an in-depth understanding of the mechanism of super low friction of liquid lubricated sliding point contacts.