Aiming at high-efficiency biomimetic CO2 reduction, a photoelectrocatalyst with excellent CO2 catalytic activity was designed and prepared by self-assembly immobilizing CoTPP onto g-C3N4 based on π–π interaction.
Aimed at high-efficiency biomimetic CO2 photoelectrochemical conversion, a bio-proton coupling metal-complex/semiconductor hybrid photoelectrocatalytic interface (Ru-BNAH/TiO2/Cu2O) was constructed by covalently modifying an in situ proton-transfer functionized molecular catalyst (Ru-BNAH) on the surface of a TiO2/Cu2O composite semiconductor substrate electrode.
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