Effective, economical and feasible remediation technology of heavy metal pollution in farmland is an important research concentration in the field of farmland soil remediation. In order to investigate the remediation effects of formula fertilizer and biochar on cadmium (Cd)–plumbum (Pb) contaminated farmland, blank (CK), lime (SH), biochar (SWT), formula fertilizer (FL), and biochar + formula fertilizer (FS) were set up in Cd–Pb contaminated farmland. The results demonstrated the following: (1) Compared with CK, SWT and FS increased the yield by 11.21% and 15.00%, respectively, which was significantly higher than other treatments. (2) The concentrations of Cd and Pb in maize kernels under all treatments were lower than the limited value stipulated by GB 2762-2022 in China. Compared with CK, FS reduced the concentration of Cd and Pb in maize kernels by 24.96% and 31.46%, respectively, which were the most significant. All the treatments can reduce the concentrations of Cd and Pb in maize cob and straw and inhibit the transfer of Cd and Pb from the lower part of the maize field to the overground part. (3) FL, SWT, and FS increased soil pH by 0.17, 0.10, and 0.19 units, respectively. FS can reduce the concentrations of available cadmium (DTPA-Cd) and available lead (DTPA-Pb) significantly, which are 31.05% and 38.57% lower than CK, respectively. (4) Each treatment can reduce the extraction state and reducible state of weak acid Cd and Pb in soil, while increasing the proportion of oxidizable state and residual state. FL and FS significantly increased the percentage of residual Cd and Pb by 18.00% and 24.32%, respectively, and 33.33% and 37.76%, respectively. (5) FL (1.747) and FS (1.679) were relatively higher than CK in input/output. In conclusion, the combined application of biochar and formula fertilizer in Cd/Pb polluted farmland can effectively reduce the concentration of Cd and Pb in maize and has high economic benefits and practicability.
Screening for low-accumulation varieties is an effective way to reduce the cadmium (Cd) content in crops and decrease human Cd intake. In this study, a field experiment was conducted to analyze the characteristics of Cd absorption and accumulation in 24 maize varieties at maturity in farmland with different levels of Cd pollution. Cluster analysis and Pareto analysis methods were used to screen for maize varieties with low Cd absorption. In addition, the environmental threshold of Cd in farmland in the study area was estimated based on the Species Sensitivity Distribution (SSD) characteristics of different maize Cd enrichment coefficients (1/BCF). The results showed that maize in the study area was subject to varying degrees of Cd pollution, with total soil Cd content ranging from 1.81 to 2.71 mg·kg−1 at test site 1 and from 0.95 to 1.76 mg·kg−1 at test site 2. Only the Cd content of heavy metals in maize kernels at test site 2 did not exceed China’s national food safety standard (GB 2762-2022, 0.1 mg·kg−1), with the Cd content of different maize varieties at test site 2 ranging from 0.008 to 0.073 mg·kg−1 and the bioconcentration factor (BCF) of maize kernels for Cd ranging from 0.004 to 0.054. According to cluster analysis and Pareto analysis, the low-Cd accumulation maize varieties suitable for local planting were identified as Yufeng 303, Nongda 372, Jingnongke 728, MC121 (Fengda Seed Industry), and Jinyu 1233. In addition, the soil Cd environmental threshold for ensuring that 95% of maize would not be polluted by Cd in soil was derived as 1.39 mg·kg−1.
The accumulation of heavy metals in rice is bound to affect human health and safety. In order to ensure food security, this study explores the effect of leaf surface regulation of zinc (Zn) fertilizer on the safety of rice in cadmium (Cd)-plumbum (Pb) polluted farmland. Through field experiments, the leaf surface control treatment of zinc fertilizer was set up, and the effects of leaf surface control of zinc fertilizer on rice yield, Cd and Pb concentration in different parts and zinc, nitrogen, phosphorus and potassium concentration in brown rice were studied in the growing period of rice. The results showed as follows: (1) Spraying twice or more in the growth stage of rice could increase the yield by 6.77–7.29% compared with the blank, which was significantly higher than that of single spraying in a certain growth stage. (2) After spraying zinc fertilizer on the leaf surface, Cd and Pb concentration in brown rice decreased by 29.52–56.01% and 11.10–28.34%, respectively, compared with CK. Two or more times of spraying can make Cd concentration in brown rice meet the Chinese standard GB 2762-2022, and one time of spraying can make Pb concentration in brown rice meet the standard. (3) Leaf surface control of zinc fertilizer could reduce the Cd enrichment ability of rice plant parts, and the Cd enrichment coefficient of brown rice was significantly reduced by 28.18–55.02%. Leaf surface control of zinc fertilizer can reduce Cd and Pb concentration in brown rice by reducing the transport ability of heavy metal Cd and Pb in rice roots to straw and then to brown rice. (4) The zinc concentration in brown rice was 18.16–20.68 mg·kg−1, which was 18.21–34.64% higher than that in CK, and the zinc enrichment effect was the most significant after spraying three times. Meanwhile, the nitrogen, phosphorus and potassium concentration in brown rice also increased with the increase of spraying times. By comprehensive analysis, the leaf surface control of zinc fertilizer can reduce the Cd and Pb concentration in rice, and the Cd and Pb concentration in brown rice can meet the Chinese standard GB 2762-2022 by spraying twice. At the same time, it can improve the concentration of zinc, nitrogen, phosphorus and potassium in brown rice, is feasible and has high economic benefits.
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