A polarimeter based on Stokes-Mueller formalism and rotating-wave-plate Stokes polarimeter is successfully developed to measure the optical rotation angle in a chiral medium. The average relative error in the measured rotation angles of glucose solutions with concentrations ranging from 0 to 1.2g/dl is determined to be 3.78%. The correlation coefficient between the measured rotation angle and the glucose concentration is found to be 0.9995, while the standard deviation is just 0.00376 degrees. From the sol-gel materials containing C 17 H 17 ClO 6 with concentrations ranging from 0 to 0.0665g/ml, the average relative error in the measured rotation angles is determined to be 3.63%. Consequently, the developed system is evaluated with a precision of 5.4% approximately in rotation angle measurement.
IntroductionsIn 1997, Cameron and Cóte [1] designed a glucose sensing digital closed-loop processing system, which is based on the heterodyne interference technique and a lock-in amplifier is used to obtain the rotation angle of the glucose.
MethodAccording to the Stokes-Mueller formalism, the Stokes vector S models the polarization state of incident light and the Mueller matrix for a chiral medium is expressed as CB M , hence, the Stokes vector CB S of output light is calculated by a
A polarimeter based on Stokes-Mueller formalism and rotating-wave-plate Stokes polarimeter is successfully developed to measure the optical rotation angle in a chiral medium. The average relative error in the measured rotation angles of glucose solutions with concentrations ranging from 0 to 1.2g/dl is determined to be 3.78%. The correlation coefficient between the measured rotation angle and the glucose concentration is found to be 0.9995, while the standard deviation is just 0.00376 degrees. From the inspection of measured rotation angle in the sol-gel materials containing C 17 H 17 ClO 6 with concentrations ranging from 0 to 0.0665g/ml, the average relative error in the measured rotation angles is determined to be 3.63%. Consequently, the derived algorithm for measuring the optical rotation angle of a chiral medium is feasible.
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