A detailed study has been undertaken of the efficiency of reinforcement in nanocomposites consisting of single-walled carbon nanotubes (SWNTs) in poly(vinyl alcohol) (PVA). Nanocomposite fibers have been prepared by electrospinning and their behavior has been compared with nanocomposite films of the same composition. Stress transfer from the polymer matrix to the nanotubes has been followed from stress-induced Raman band shifts, which are shown to be controlled by both geometric factors such as the angles between the nanotube axis, the stressing direction and the direction of laser polarization, and by finite length effects and bundling. A theory has been developed that takes into account all of these factors and enables the behavior of the different forms of nanocomposite, both fibers and films, to be compared in different polarization configurations. The effective modulus of the SWNTs has been found to be in the range 530-700 GPa which, while being impressive, is lower than the generally accepted value of around 1000 GPa as a result of factors such as finite length effects and nanotube bundling. This value of effective modulus has, however, been shown to be consistent with the contribution of nanotubes to the 20% increase in Young's modulus found for the nanocomposite films with a loading of only 0.2% of SWNTs. Hence a self-consistent method has been developed which enables the efficiency of reinforcement by nanotubes, and potentially other high-aspect-ratio nanoparticles, to be evaluated from stress-induced Raman bands shifts in nanocomposites independent of the specimen geometry and laser polarization configuration.

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Remanufacturing is recognized as a major circular economy option to recover and upgrade functions from post-use products. However, the inefficiencies associated with operations, mainly due to the uncertainty and variability of material flows and product conditions, undermine the growth of remanufacturing. With the objective of supporting the design and management of more proficient and robust remanufacturing processes, this paper proposes a generic and reconfigurable simulation model of remanufacturing systems. The developed model relies upon a modular framework that enables the user to handle multiple process settings and production control policies, among which token-based policies. Customizable to the characteristics of the process under analysis, this model can support logistics performance evaluation of different production control policies, thus enabling the selection of the optimal policy in specific business contexts. The proposed model is applied to a real remanufacturing environment in order to validate and demonstrate its applicability and benefits in the industrial settings.

In the present work, the reinforcement potential of thermally recycled glass fibers in injection molded Polypropylene (PP) composites was investigated. Microbond tests showed that fiber sizing lost its compatibility to the PP matrix after exposure to temperatures of 250°C in air. The drop of the adhesion between fibers and PP was mirrored by a large reduction of the tensile strength of the injection molded PP composites. In inert atmosphere the degradation of the fiber sizing and the reduction of the IFSS were less rapid than in air but no significant difference was observed above 400°C. It was concluded that thermally recycled glass fibers will require a post‐treatment to act as an effective reinforcement in injection molded PP composites even if the thermal recycling was performed in an inert atmosphere. The post‐treatment will need to improve the compatibility of the fibers to the polymer matrix and the fiber strength. POLYM. COMPOS., 39:1032–1040, 2018. © 2016 Society of Plastics Engineers

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