A combinative approach of steam-assisted crystallization and hard templating was employed to prepare mesostructured Ga/ZSM-5 catalysts. Carbon nanotubes (CNTs) containing gallium oxide nanoparticles supported on the exterior surface and confined in the inner space were used as the templates. A comparative study showed that by using these two templates, the crystallinities, mesoporosities, and Ga coordination environments of mesostructured Ga/ZSM-5 catalysts were similar. However, a greater strength of Lewis acid of Ga/ZSM-5 was obtained using the GaO x -encapsulated CNTs as the template. Encapsulated GaO x was less reducible than those supported on the exterior surface of the CNTs, resulting in an increased concentration of isolated (GaO) + . Moreover, compared to pristine ZSM-5, the concentration of Brønsted acid was nearly intact by using GaO x -encapsulated CNTs as the templates. A better methanol aromatization performance was achieved by the Ga/ZSM-5 made by using GaO xencapsulated CNTs.
Overexploitation has led to the destruction of resources and endangered ecological environments. Therefore, research for renewable material has become more important in the construction industry. This study used sintered lightweight aggregate made of clay to replace the coarse and fine aggregate and processed aluminum-wastage to make the foaming agents for cement, producing a brand-new extra-lightweight expanded no-fines cellular concrete. The cellular concrete not only utilizes recycled materials, but also produces an environment-friendly, green building material. Validated throughout the experiment, the cellular concrete may provide functions such as fire protection, thermal resistance, and acoustic absorption when used as non-structural material. This paper attempts to evaluate the basic physical properties of cellular concrete by different water/cement ratio (W/C) and agent/cement (A/C) ratio for the coefficients of expansion, compression strengths, and the thermal conductivity.
This paper study was commenced to treat fatal contamination at the Er-Jen River, supplied water for agricultural irrigation, aquaculture and industrial in Kaohsiung and Tainan Area, when the Sixth River Management of Water Resources Agency (WRA) developed the project to build flood embankment. The fatal contamination was throw into the discard by illegal manufacturer which discarded the wastage of printed circuit boards, toxic heavy metal contained sludge, and waste aluminum slag. The treatment project was conducted by Industrial Technology Research Institute (ITRI) on preliminary tests, cleanup planning, and process supervision to ensure contamination removal, flood protection, and landscape improvement. The accumulative volume cleaned and screened on this site reached 45,159 cubic meters, whereas 378.25 tons of waste printed circuit boards, 12,833 tons of toxic heavy metal contained sludge, and 31,000 tons of general industrial wastages. The waste printed circuit boards through stripping/acid washing and screening, there are 334.653 tons valuable (including 0.143 tons of copper and 334.51 tons of wire casting materials) from the recycle extract and 43.597 tons of wastes that were not valuable for reutilize. Toxicity characteristic leaching procedure (TCLP) tests were conducted on the site after cleanup to verify the treatment work successful, because the rate of contamination removal was greater than 90%.
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