Hanford low-activity waste (LAW) glasses with high sulfur concentrations are subject to salt segregation in the melter, which hinders melter operation by corroding components and shortening the melter life. To better predict the point at which salt accumulates on the melt surface, the development of sulfate solubility models is needed. Using a sulfur saturation method, crucible scale melts for 13 LAW glasses with varying sulfur solubilities were conducted. The resulting salt and glass compositions were reported and the change in component partitioning following the saturation process was examined to better understand potential changes in overall glass composition. It was shown that both Cr 2 O 3 and Cl experience significant losses, with ~28% of Cr 2 O 3 partitioning into the salt phase and Cl primarily volatilizing out of the melt (~23% partitioned to salt and ~40% lost as off gas). These patterns can be accounted for during model development. Measured sulfur solubilities were also compared to previously reported data. It was found that crucible sulfur solubility ranged from 0.95 to 2.14 wt% SO 3 with a high correlation ([R 2 fit = 0.94]) between crucible solubility and melter tolerance. These results suggest that crucible scale sulfate solubility data can be used to predict SO 3 tolerance in the melter feed. K E Y W O R D Scharacterization, glass forming melts-chemical analysis, glass forming systems-volatilization, modeling, properties-borosilicate, properties-glass forming melts

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A major challenge in developing biomimetic, highperformance, and sustainable products is the accurate replication of the biological materials' striking properties, such as high strength, self-repair, and stimuli-responsiveness. The rationalization of such features on the microscopic scale, together with the rational design of synthetic materials, is currently hindered by our limited understanding of the sequence-structure-property relationship. Here, employing state-of-the-art nuclear magnetic resonance (NMR) spectroscopy, we link the atomistic structural and dynamic properties of an artificial bioinspired tandem repeat protein TR(1,11) to its stunning macroscopic properties including high elasticity, self-healing capabilities, and recordholding proton conductivity amongst biological materials. We show that the hydration-induced structural rearrangement of the amorphous Gly-rich soft segment and the ordered Ala-rich hard segment is the key to the material's outstanding physical properties. We found that in the hydrated state both the Ala-rich ordered and Gly-rich disordered parts contribute to the formation of the nanoconfined β-sheets, thereby enhancing the strength and toughness of the material. This restructuring is accompanied by fast proline ring puckering and backbone cis-trans isomerization at the water-protein interface, which in turn enhances the elasticity and the thermal conductivity of the hydrated films. Our in-depth characterization provides a solid ground for the development of next-generation materials with improved properties.