The effective activation and utilization of O2 have always been the focus of scientists because of its wide applications in catalysis, organic synthesis, life and medical science. Here, a novel method for activating O2 spontaneously via interfacial oxygen vacancies on carbon-coated TiO2–x to generate reactive oxygen species (ROS) with versatile applications is reported. The interfacial oxygen vacancies can be stabilized by the carbon layer and hold its intrinsic properties for spontaneous oxygen activation without light irradiation, while common surface oxygen vacancies on TiO2–x are always consumed by the capture of H2O to form the surface hydroxyls. Thus, O2 absorbed at the interface of carbon and TiO2–x can be directly activated into singlet oxygen (1O2) or superoxide radicals (·O2 –), confirmed both experimentally and theoretically. These reactive oxygen species exhibit excellent performance in oxidation reactions and inhibition of MCF-7 cancer cells, providing new insight into the effective utilization of O2 via oxygen vacancies on metal oxides.

The rapid settlement of tailings is an important technical guarantee for the continuous production of downhole filling. The selection of a reasonable flocculant is essential for accelerating the settlement speed of classified fine tailings. The present paper conducts indoor static sedimentation experiments, NMR observation, electron microscope scanning, and other methods to analyze the porosity and pore-size distribution characteristics of floc solution for classified fine tailing under four flocculants, namely, ZYZ, ZYD, JYC-1, and JYC-2. The dimension, spatial distribution characteristics, particle size characteristics, and morphological characteristics of the scanning electron microscope images of floc were studied. Results show that the unit consumption of flocculant at 30 g/t is the critical value for increasing the flocculation and sedimentation effect of the classified fine tailings solution. The highest distribution percentage of small-sized classified fine tailings and the lowest average pore size was observed under the ZYZ-type flocculant. This flocculant also obtained the lowest porosity, largest average floc size, largest area occupied by the floc, lowest pore percentage, and the densest floc structure. Thus, this flocculant showed the best flocculation effect. A negative correlation was observed between the equivalent diameter of floc with varying settlement heights. The dimension of floc increased with the decrease in bed settlement height, and the overall structure of the floc gradually transitioned from loose to dense from top to bottom. The present paper characterizes the microscopic morphology and spatial structure characteristics of floc under different flocculants from a microscopic point of view. The present paper also provides a scientific basis for the selection of the optimal flocculant.

Aiming to solve the problems related to the slow settling speed and the long-term consumption of ultra-fine tailings in mine filling, the effect of flocculant type on the flocculation and settling performance of ultra-fine tailings was studied through static sedimentation experiments on tailings. The microstructure of the flocculation was observed and analyzed using an electron microscope. On this basis, the selection of the optimum flocculant type and dosage parameters was carried out. The results show that the best addition amount of the AZ9020 anionic flocculant was 30 g/t, a solution concentration of 0.3%, and a stirring time of more than 45 min. The floc structure of the full-tailings flocculation solution was formed by the AZ9020 anionic flocculant. Moreover, the size of less than 0.1 μm was still relatively large; thus, the overall size of the structure was small and uniformly dispersed. The floc solution had the smallest porosity, the fractal dimension was the largest, the molecular weight of the floc was the largest, and the floc was the most compact, making it appropriate for the rapid removal of floc structures from water. Sedimentation is also the best flocculant for flocculation and sedimentation. The size of the flocs decreased as the height of the flocculation sediment bed increased during flocculation and sedimentation. The research results provide a microscopic view for the selection of the best flocculant type.

To explore the hydration characteristics and early strength evolution of classified fine tailings cemented backfill (CFTCB), a nuclear magnetic resonance (NMR) analysis and a volume resistivity test were performed on classified fine tailings filling slurry (CFTFS). The early hydration products of CFTCB were studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD) phase analysis. Uniaxial compressive strength (UCS) test was carried out, and the microscopic characteristics and strength rules of the hydration reaction of CFTCB were analyzed. Based on the experiment, we found the law of water content change and porosity evolution. The early hydration reaction can be divided into the dissolution, setting, and hardening stages. The volume resistivity test results show that the volume resistance of filling slurry increases slowly at first then decreases, and finally increases rapidly. The variation trend of volume resistivity is related to the degree of hydration reaction. When combined with the hydration characteristics of backfill materials, the hydration reaction rate determines the growth rate of early strength of backfill, and the formation of hydration products is the reason for the early strength increase in backfill. The research conclusion has an important theoretical guiding value and engineering significance in mine filling production organization and filling ratio parameter optimization.