Abstract. In this paper, we present mean gas and dust opacities relevant to the physical conditions typical of protoplanetary discs. As the principal absorber for temperatures below ∼1500 K, we consider spherical and aggregate dust particles of various sizes, chemical structure, and porosity, consisting of ice, organics, troilite, silicates, and iron. For higher temperatures, ions, atoms, molecules, and electrons are included as the main opacity sources. Rosseland and Planck mean opacities are calculated for temperatures between 5 K and 10 000 K and gas densities ranging from 10 −18 g cm −3 to 10 −7 g cm −3 . The dependence on the adopted model of dust grains is investigated. We compare our results with recent opacity tables and show how different opacity models affect the calculated hydrodynamical structure of accretion discs.

We present near-UV transmission spectroscopy of the highly irradiated transiting exoplanet WASP-12b, obtained with the Cosmic Origins Spectrograph (COS) on the Hubble Space Telescope (HST). The spectra cover three distinct wavelength ranges:NUVA (2539-2580 Å); NUVB (2655-2696 Å); and NUVC (2770-2811 Å). Three independent methods all reveal enhanced transit depths attributable to absorption by resonance lines of metals in the exosphere of WASP-12b. Light curves of total counts in the NUVA and NUVC wavelength ranges show a detection at a 2.5σ level. We detect extra absorption in the Mg II λλ2800 resonance line cores at the 2.8σ level.The NUVA, NUVB and NUVC light curves imply effective radii of 2.69±0.24 R J , 2.18±0.18 R J , and 2.66±0.22 R J respectively, suggesting the planet is surrounded by an absorbing cloud which overfills the Roche lobe. We detect enhanced transit depths at the wavelengths of resonance lines of neutral sodium, tin and manganese, and at singly ionised ytterbium, scandium, manganese, aluminum, vanadium and magnesium. We also find the statistically expected number of anomalous transit depths at wavelengths not associated with any known resonance line. Our data are limited by photon noise, but taken as a whole the results are strong evidence for an extended absorbing exosphere surrounding the planet. The NUVA data exhibits an early ingress, contrary to model expectations; we speculate this could be due to the presence of a disk of previously stripped material. Subject headings: stars: individual (WASP-12) 1 http://archive.stsci.edu/ 2 See the COS Data Handbook for more information on CALCOS:

We introduce a fast and versatile computer code, GGchem, to determine the chemical composition of gases in thermo-chemical equilibrium down to 100 K, with or without equilibrium condensation. We review the data for molecular equilibrium constants, k p (T ), from several sources and discuss which functional fits are most suitable for low temperatures. We benchmark our results against another chemical equilibrium code. We collect Gibbs free energies, ∆G• − f , for about 200 solid and liquid species from the NIST-JANAF database and the geophysical database SUPCRTBL. We discuss the condensation sequence of the elements with solar abundances in phase equilibrium down to 100 K. Once the major magnesium silicates Mg 2 SiO 4 [s] and MgSiO 3 [s] have formed, the dust/gas mass ratio jumps to a value of about 0.0045 which is significantly lower than the often assumed value of 0.01. Silicate condensation is found to increase the carbon/oxygen ratio (C/O) in the gas from its solar value of ∼ 0.55 up to ∼ 0.71, and, by the additional intake of water and hydroxyl into the solid matrix, the formation of phyllosilicates at temperatures below ∼ 400 K increases the gaseous C/O further to about 0.83. Metallic tungsten (W) is the first condensate found to become thermodynamically stable around 1600 − 2200 K (depending on pressure), several hundreds of Kelvin before subsequent materials like zirconium dioxide (ZrO 2 ) or corundum (Al 2 O 3 ) can condense. We briefly discuss whether tungsten, despite its low abundance of ∼ 2 × 10 −7 times the silicon abundance, could provide the first seed particles for astrophysical dust formation. The GGchem code is publicly available at https://github.com/pw31/GGchem.