We study the energy structure and the transfer of an extra electron or hole along periodic polymers made of N monomers, with a repetition unit made of P monomers, using a Tight-Binding wire model, where a site is a monomer (e.g., in DNA, a base pair), for P even, and deal with two categories of such polymers: made of the same monomer (GC..., GGCC..., etc) and made of different monomers (GA..., GGAA..., etc). We calculate the HOMO and LUMO eigenspectra, density of states and HOMO-LUMO gap and find some limiting properties these categories possess, as P increases. We further examine the properties of the mean over time probability to find the carrier at each monomer. We introduce the weighted mean frequency of each monomer and the total weighted mean frequency of the whole polymer, as a measure of the overall transfer frequency content. We study the pure mean transfer rates. These rates can be increased by many orders of magnitude with appropriate sequence choice. Generally, homopolymers display the most efficient charge transfer. Finally, we compare the pure mean transfer rates with experimental transfer rates obtained by time-resolved spectroscopy.

In this work we present a temperature and angular dependent study of the structural and magnetic properties in highly crystalline V2O3/Ni/Zr magnetic heterostructure films. Our investigation focuses on the coupling between the ferromagnetic Ni layer and V2O3 layer which undergoes an antiferromagnetic/paramagnetic phase transition coupled to the structural phase transition of the material at around 150 K. Structural investigations using x-ray diffraction reveal highly crystalline films of a quality which has previously not been reported in the literature. The Ni layers display an absence of in-plane magnetic anisotropy owing to the highly textured (1 1 1) layering of the Ni films on the underlying V2O3 (0 0 0 1) oriented layer. During the transition we observe a strain related enhancement of the coercivity and the onset of a weak exchange bias for cooling under an external magnetic field. Heating the films to above the transition temperature, the exchange bias in the Ni is removed and can be reversed upon subsequent cooling under an inverted external magnetic field. Using temperature dependent polarized neutron reflectometry we investigate the film structure at the interface, capturing the magnetic and nuclear profiles.

We study the steering of visible light using a combination of magneto-optical effects and the reconfigurability of magnetic domains in yttrium-iron garnet films. The spontaneously formed stripe domains are used as a field-controlled optical grating, allowing for active spatiotemporal control of light. We discuss the basic ideas behind the approach and provide a quantitative description of the field dependence of the obtained light patterns. Finally, we calculate and experimentally verify the efficiency of our magneto-optical grating.

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