ABSTRACT:Meltblowing is a most versatile and costeffective process commercially available worldwide to produce microfiber nonwovens directly from thermoplastic resins. The new bicomponent (bico) meltblown technology opens a great possibility to make even finer microfibers by subsequently fiber splitting. Water-dispersive Eastman AQ polymers were initially introduced to the meltblown process to make the mono-and bicomponent meltblown webs at Textiles and Nonwovens Development Center (TANDEC), University of Tennessee, Knoxville. The postwater treatment was performed on the fabrics, which resulted in the dispersive part (AQ polymer) being dispersed in water and only the other part remaining in the bico web. A process-structure-property study is provided toward the research reported in this article.
Poly(trimethylene terephthalate) (PTT)-based mono and bico meltblown webs have been produced by using a Reicofil® Bi-Component Meltblown Line at TANDEC, located at the University of Tennessee, Knoxville, TN. Thermal and flow properties of PTT were first examined by DSC (differential scanning calorimetry) and with a Melt Indexer for an effective experimental design through the Surface Response Methodology (SRM). The processability of meltblowing in a wide range of operating windows was extensively investigated. Melt temperature, melt throughput, air temperature, airflow rate, and DCD (distance of collector to die) were considered as primary process control variables. The produced webs were characterized for fiber diameter, bulk density, air permeability, hydrostatic head, tensile properties, and heat shrinkage. Non-round and curly or twisted fibers were observed in the bico PP/PTT webs by SEM (scanning electrical microscope). The PTT grade studied is quite suitable for the meltblown process. The PTT/PP-based bico webs showed enhanced barrier properties and heat resistance.
Side-by-side bicomponent meltblown fiber webs were developed on REICOFIL ® bicomponent (bico) meltblown line at The University of Tennessee's Textiles and Nonwovens Development Center (TANDEC), using polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyamide (PA), polytrimethylene terephthalate (PTT), and so forth. The posttreatment was performed by hydroentanglement to investigate the fiber-splitting behavior in this research. Microscopy analysis and SEM were applied to examine the web structure. The change in web property after posttreatment and the adhesion mechanism of the polymer interface were also addressed.
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