Adhesive bonding of plastic components is a well-established process for various applications. Specifically for thermoplastic parts, surface pre-treatment is required to achieve optimum bonding quality. However, automated surface pre-treatment is not established yet. Reasons are missing process monitoring and significant challenges arising from conventional monitoring techniques that hardly identify surface contaminants. In a recent research project, the authors investigated how process monitoring by spectrometry during a laser-based surface pre-treatment might solve this challenge for fiber-reinforced plastics and generic surface contaminants. This article describes experiments conducted on two composite materials with different contaminants. A nanosecond-pulsed UV-laser was used to pretreat a glass-fiber reinforced 2C-polyurethane (GF-PUR) and a glass-fiber reinforced polyamide 6 (GF-PA6). Each composite had coupons contaminated with an industry standard mould release agent or artificial silicate-based dust as well as uncontaminated samples. The samples were laser pretreated and compared to reference coupons that did not receive laser treatment. The samples were analyzed after laser pre-treatment for their free surface energies by the detection of the contact angle and measured for the surface roughness. The bonding improvement due to the laser process was determined by shear strength and peel resistance tests. The results show that UV-laser pre-treatment has an advantageous impact on the bonding strength of GF-PUR and GF-PA6. Combined with a fast spectrometric process monitoring that robustly identifies contaminants during the laser process, an inline process control is feasible.

Fiber-reinforced plastics (FRP) are widely used in the automotive industry due to their lightweight construction potential. Especially, injection-molded components are very popular because of their short cycle times. Unfortunately, this manufacturing process results in some disadvantages for delayed adhesive bonding. On the one hand, such thermoplastics have a very low surface energy (Polyamide 6 (PA6) 36 mJ/m), on the other hand residues of release agents on the surface hinder adhesion between product and adhesive. These disadvantages have to be overcome by the right surface pre-treatment process. Currently, a solvent-containing process is usually used for this purpose. If necessary, the use of primer is common. In the presented paper, the pre-treatment process of an injection-molded component made of polyamide 6 reinforced with glass short-fibers is presented. First, material-specific properties are measured. The influence of laser pre-treatment at 355 nm and 1064 nm wavelength is investigated. Measurements of surface free energy and surface roughness are conducted. The bonding strength is validated by peel test and tensile shear tests. The shear strength was doubled by laser pre-treatment at a medium energy level, partially cohesive failure of the adhesive was achieved. Both investigated wavelengths led to a great improvement of bonding strength at suitable parameters.

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