De-carbonization of the power generation sector becomes increasingly important in order to achieve the European climate targets. Coal or biomass gasification together with a pre-combustion carbon capture process might be a solution resulting in hydrogen-rich gas turbine (GT) fuels. However, the high reactivity of these fuels poses challenges to the operability of lean premixed gas turbine combustion systems because of a higher auto-ignition and flashback risk. Investigation of these phenomena at GT relevant operating conditions is needed to gain knowledge and to derive design guidelines for a safe and reliable operation. The present investigation focusses on the influence of the fuel injector configuration on auto-ignition and kernel development at reheat combustor relevant operating conditions. Auto-ignition of H2-rich fuels was investigated in the optically accessible mixing section of a generic reheat combustor. Two different geometrical in-line configurations were investigated. In the premixed configuration, the fuel mixture (H2 / N2) and the carrier medium nitrogen (N2) were homogeneously premixed before injection, whereas in the co-flow configuration the fuel (H2 / N2) jet was embedded in a carrier medium (N2 or air) co-flow. High-speed imaging was used to detect auto-ignition and to record the temporal and spatial development of auto-ignition kernels in the mixing section. A high temperature sensitivity of the auto-ignition limits were observed for all configurations investigated. The lowest auto-ignition limits are measured for the premixed in-line injection. Significantly higher auto-ignition limits were determined in the co-flow in-line configuration. The analysis of auto-ignition kernels clearly showed the inhibiting influence of fuel dilution for all configurations.

It is generally accepted that combustion of hydrogen and natural gas mixtures will become more prevalent in the near future, to allow for a further penetration of renewables in the European power generation system. The current work aims at the demonstration of the advantages of steam dilution, when highly reactive combustible mixtures are used in a swirl-stabilized combustor. To this end, high-pressure experiments have been conducted with a generic swirl-stabilized combustor featuring axial air injection to increase flashback safety. The experiments have been conducted with two fuel mixtures, at various pressure levels up to 9 bar and at four levels of steam dilution up to 25% steam-to-air mass flow ratio. Natural gas has been used as a reference fuel, whereas a mixture of natural gas and hydrogen (10% hydrogen by mass) represented an upper limit of hydrogen concentration in a natural gas network with hydrogen enrichment. The results of the emissions measurements are presented along with a reactor network model. The latter is applied as a means to qualitatively understand the chemical processes responsible for the observed emissions and their trends with increasing pressure and steam injection.

Autoignition and flame stabilisation in a gas turbine combustor presents severe challenges for safe and reliable gas turbine operation as soon as they occur in parts of the combustor that are not designed to sustain higher thermal loads. Especially when operating on highly-reactive fuels like hydrogen, higher autoignition and flashback risk associated with these fuels have to be taken into account. In the present study, flame stabilisation initiated by autoignition events is investigated in an optically accessible mixing duct of a generic reheat combustor at typical reheat conditions. The experiments were conducted at pressures of 15 bar, vitiated air temperatures higher than 1100 K and bulk velocity of 200 m/s. The fuel was a hydrogen-nitrogen mixture with up to 70 vol. % hydrogen and was injected by a coflow inline injector along with preheated carrier air of temperatures up to 623 K. The autoignition-driven flame stabilisation process was investigated by recording the luminescence signal with high-speed cameras and by tracking the temporal and spatial development of autoignition kernels in the mixing duct. A detailed and comprehensive data set could be generated providing the basis for an in-depth analysis of the stabilisation process on time scales down to 0.3 milliseconds, which is fast enough to disclose the small timescales at which the autoignition kernels develop in the mixing section. A stabilising sequence was found to lead to the stabilised flames due to a non-interrupted sequence of autoignition kernels. The stabilising sequence was found behave differently in two different temperature regimes where sequence durations and amounts of kernels differed significantly from each other. A state in which the cross section of the mixing section is fully blocked by one or more kernels in vertical direction could be identified for all operating conditions and the development of subsequent autoignition kernels after the section blockage changed clearly once this state was reached.

Gas turbines will play a significant role in future power generation systems because they provide peak capacity due to their fast start-up capability and high operational flexibility. However, in order to meet the COP 21 goals, de-carbonization of as turbine fuels is required. Compared to natural gas operation, autoignition and flashback risks in gas turbines operated on hydrogen-rich fuels are higher which has to be taken into account for a proper gas turbine design. From investigations of these phenomena at relevant operating conditions with appropriate measurement techniques, e.g. high-speed imaging, the understanding of the non-stationary processes occurring during autoignition can be improved and design guidelines for a safe and reliable gas turbine operation can be derived. The present study investigates the influences of elevated carrier-air preheating temperatures and hydrogen fuel volume fractions on autoignition at hot gas temperatures higher than 1100 K and pressures of 15 bar. An in-line co-flow injector is used to inject the hydrogen-nitrogen fuel mixtures. The formation, temporal and spatial development of autoignition kernels at high-temperature vitiated air conditions, e.g. relevant to reheat combustor operation, are studied. The experiments were conducted in an optically accessible mixing section of a generic reheat combustor. The hydrogen-nitrogen fuel mixtures of up to 70 vol. % hydrogen are injected in-line into the mixing section along with the carrier-air which was preheated to temperatures between 303 K and 703 K. High-speed imaging was used to detect the autoignition kernels and their temporal and spatial development from luminescence signals. Particle Image Velocimetry measurements were conducted to obtain the velocity distribution in the mixing section at autoignition conditions. The influences of vitiated air temperatures and carrier preheating temperatures on autoignition and flame stabilisation limits are shown, alongside the spatial distribution of different types of autoignition kernels, developing at different stages of the autoignition process. The development of autoignition kernels could be linked to the shear layer development derived from global experimental conditions.

It is generally accepted that combustion of hydrogen and natural gas mixtures will become more prevalent in the near future, to allow for a further penetration of renewables in the European power generation system. The current work aims at the demonstration of the advantages of steam dilution, when highly reactive combustible mixtures are used in a swirl-stabilized combustor. To this end, high-pressure experiments have been conducted with a generic swirl-stabilized combustor featuring axial air injection to increase flashback safety. The experiments have been conducted with two fuel mixtures, at various pressure levels up to 9 bar and at four levels of steam dilution up to 25% steam-to-air mass flow ratio. Natural gas has been used as a reference fuel, whereas a mixture of natural gas and hydrogen (10% hydrogen by mass) represented an upper limit of hydrogen concentration in a natural gas network with hydrogen enrichment. The results of the emissions measurements are presented along with a reactor network model. The latter is applied as a means to qualitatively understand the chemical processes responsible for the observed emissions and their trends with increasing pressure and steam injection.