ated with soil type, vadose zone flow and transport processes are also affected by such external factors as tillage Vadose zone flow and transport processes are known to be strongly practices.

Compost application tends to increase soil fertility and is likely to modify soil hydrodynamic properties by acting on soil structural porosity. Two composts, a municipal solid waste compost (MSW) and a co-compost of green wastes and sewage sludge (SGW), have been applied every other year for 6 yr to cultivated plots located on a silt loam soil in the Parisian Basin, France. Four soil zones were defined in the topsoil after plowing: the plowpan located at the base of the plowed layer, compacted (Delta) or noncompacted (Gamma) zones located within the plowed layer, and interfurrows created by plowing and containing a large quantity of crop residues together with the recently-applied compost. To assess the effect of compost application on the near-saturated soil hydraulic conductivity, infiltration rates were measured using a tension disc infiltrometer at three water pressure potentials -0.6, -0.2, and -0.05 kPa in the various zones of the soil profile. Compost addition decreased K((sat)) in the interfurrows after plowing by almost one order of magnitude with average values of 5.6 x 10(-5) m.s(-1) in the MSW plot and 4.1 x 10(-5) m.s(-1) in the SGW plot, against 2.2 x 10(-4) m.s(-1) in the control plot. This effect had disappeared 6 mo after plowing when the average K((sat)) in the control plot had decreased to 1.9 x 10(-5) m.s(-1) while that in the compost-amended plots remained stable.

No abstract

Compost amendment on agricultural soil is a current practice to compensate the loss of organic matter. As a consequence, dissolved organic carbon concentration in soil leachates can be increased and potentially modify the transport of other solutes. This study aims to characterize the processes controlling the mobility of dissolved organic matter (DOM) in deep soil layers and their potential impacts on the leaching of organic contaminants (pesticides and pharmaceutical compounds) potentially present in cultivated soils receiving organic waste composts. We sampled undisturbed soil cores in the illuviated horizon (60-90 cm depth) of an Albeluvisol. Percolation experiments were made in presence and absence of DOM with two different pesticides, isoproturon and epoxiconazole, and two pharmaceutical compounds, ibuprofen and sulfamethoxazole. Two types of DOM were extracted from two different soil surface horizons: one sampled in a plot receiving a co-compost of green wastes and sewage sludge applied once every 2 years since 1998 and one sampled in an unamended plot. Results show that DOM behaved as a highly reactive solute, which was continuously generated within the soil columns during flow and increased after flow interruption. DOM significantly increased the mobility of bromide and all pollutants, but the effects differed according the hydrophobic and the ionic character of the molecules. However, no clear effects of the origin of DOM on the mobility of the different contaminants were observed.