The TeII/TeIII‐catalyzed dehydrogenative C−H phenothiazination of challenging phenols featuring electron‐withdrawing substituents under mild aerobic conditions and with high yields is described. These unexpected TeII/TeIII radical catalytic properties were characterized by cyclic voltammetry, EPR spectroscopy, kinetic experiments, and DFT calculations.

A series of [(PMP)Rh(CO)Cl] complexes was synthesised and the impact of the metalloligands Cu, Li and Zn on the CO stretching band was analysed.

Background: Connecdenns are GEFs for Rab35, a GTPase controlling endocytic recycling. Regulation of connecdenn function is unknown. Results: The GEF activity of connecdenn 1 and 2 are autoinhibited, and this is regulated by Akt activation downstream of insulin stimulation. Conclusion: Phosphorylation of connecdenn by Akt may provide a mechanism to control cargo recycling. Significance: Signaling pathways impinge on membrane-trafficking pathways.