Activated carbon honeycomb supported manganese and cerium
oxides
(MnO
x
–CeO2/ACH) catalysts
were investigated for selective catalytic reduction (SCR) of NO at
low temperatures of 80–200 °C. Compared with ACH supported
manganese oxide catalyst (MnO
x
/ACH), MnO
x
–CeO2/ACH catalysts show
much higher SCR activity and higher selectivity to N2.
NO conversion can be improved by the addition of CeO2 from
less than 50% to 100% at 80–160 °C. The N2 selectivity
of higher than 99.8% is obtained over the Ce(1)Mn/ACH catalyst at
80–200 °C. Results indicate that the addition of CeO2 improves the distribution of MnO
x
and enhances the oxidation of NO to NO2, producing more
absorbed NO3
– on the catalyst surface,
which is then reduced into N2 by NH3. These
behaviors account for the promoting effect of CeO2 on the
SCR activity.
A facile in situ surface anchoring process is proposed for the fabrication of novel hard carbon/graphite composites. Such unique composites can be used as promising anodes for lithium-ion batteries with high performance.
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