Acid Mine Drainage (AMD) is a great concern in many abandoned mines because of its adverse effect on the environment. In mining processes, many kinds of wastes are produced. These wastes may become eventually sources of environmental degradation. The focus of this study is the geochemical characterization of the end-processed tailings generated by Akara Gold Mine, the biggest gold mine in Thailand. Tailing samples were systematically collected for analyses of chemical and mineralogical compositions. As a result, their quantitative chemical analyses are slightly different from place to place, but mineral components cannot be clearly differentiated. For instance, it may be assumed that the end-processed tailings, which were a mixture between high and low grade concentrates, would have similar mineral components. However, the little variation of chemical composition may be caused by the ore refining processes that are somehow varied in proportion to chemical additives, alkali cyanide and quick lime in particular. In addition, clay composition in ore-bearing layers may also influence alumina content of tailings, accordingly. Distribution of the tailings is not related to depth and distance of the tailing storage pond because the disposal has sped them over the pond during operation. Total heavy metals of the tailing samples were analyzed on the basis of the EPA 3052 method. Consequently, the most toxic elements (e.g., Co, Cu, Cd, Cr, Pb, Ni and Zn) were found falling within the standard of Thailand Soil Quality Standards for Habitat and Agriculture. Only Mn appears to have higher content than the standard. In addition, leaching tests proved that these tailings contain low metal concentrations. As a result, at pH 2, Mn can leach out exceeding the Thailand Surface Water Quality Standard for Agricultural (Mn \1 ppm) and the Thailand Industrial Effluent Standard (\5 ppm). Although leachate at pH 4 and neutral conditions contains lower Mn than the Industrial Effluent Standard it still exceeds the surface water quality standard. Interestingly, Pb can be leached out exceeding both standards (0.2 ppm for the industrial effluent standard and 0.05 ppm for the surface water quality standard). For Ni leaching, its concentration is lower than the Industrial Effluent Standard at all pH conditions but still exceeds the Surface Water Standard at pH 2 and 4. This information should be taken into consideration for further environmental monitoring. Acid generating potential of the tailings was estimated using acid-base accounting (ABA) and net acid generation (NAG) tests. The results of ABA and NAG tests show that the tailing samples contain a high amount of sulfur. However, they also contain high acid neutralization capacity. Consequently, these tailings may not have potential to generate acid drainage; in the other words, they can be classified as a non-acid forming (NAF) material. However, since these tailings contain some heavy metals
Acid mine drainage (AMD) is the environmental issue that generates the greatest public concern regarding the mining industry. Thus, characterization of mine waste rock according to acid generation potential is necessary for mining operations to ensure proper waste rock storage and to avoid future adverse environmental effects. Therefore, this study was conducted to estimate the potential of AMD generation in the largest operating gold mine in Thailand by using acid base accounting and net acid generation tests. Representative samples of six types of waste rock classified by mining geologists for mineral processing and waste dumping were collected for this study: volcanic clastic, porphyritic andesite, andesite, silicified tuff, silicified lapilli tuff, and sheared tuff. Under various conditions, experimental results indicate that only silicified lapilli tuff and shear tuff are potentially acid-forming materials. The results indicate that AMD generation may possibly occur a long time after mine closure due to the lag time of the dissolution of acid-neutralizing sources. Acidic generation from some waste rocks may occur in the future based on environmental conditions, particularly the oxidation of sulphide minerals by the combination of oxygen and water. Therefore, a proper design for waste rock dumping and storage is necessary to reduce the risk of AMD generation in future. It is advisable to install a surface management system to control the overland flow direction away from the waste dump area and tailing storage facility and to install a second water storage pond next to the main storage pond to store the spilled water during storms and the rainy season. A water quality monitoring plan that focuses on disturbed areas such as water storage ponds and mine pits should be put in place.
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