Transparent flexible electronics
constitute a significant research
field. Flexible deep-ultraviolet (UV) detectors have received much
attention due to their potential in the applications of healthcare,
communications, astronomy, and environment monitoring. Recent studies
have investigated a variety of flexible photodetectors but show that
the transparent, flexible, chemical, and thermal stability performances
of these detectors cannot meet the requirements for practical applications.
In this study, we demonstrate transparent flexible deep-UV detectors
based on the combination of high-quality epitaxial n-type β-Ga2O3 and p-type NiO films as a photodiode on a flexible
muscovite substrate. The electrical current of this heterojunction
is increased over a 1000 times for on/off ratio under 265 nm wavelength
illumination with a reasonable response (<1 s). Moreover, these
photodetectors also exhibit good thermal stability as well as excellent
mechanical flexibility. Our results exhibit the superior performance
of the oxide-based solar-blind deep-UV detectors for advanced flexible
sensing and smart applications.
Relaxor
ferroelectric-based energy storage systems are promising
candidates for advanced applications as a result of their fast speed
and high energy storage density. In the research field of ferroelectrics
and relaxor ferroelectrics, the concept of solid solution is widely
adopted to modify the overall properties and acquire superior performance.
However, the combination between antiferroelectric and paraelectric
materials was less studied and discussed. In this study, paraelectric
barium hafnate (BaHfO3) and antiferroelectric lead hafnate
(PbHfO3) are selected to demonstrate such a combination.
A paraelectric to relaxor ferroelectric, to ferroelectric, and to
antiferroelectric transition is observed by varying the composition x in the (Ba1–x
Pb
x
)HfO3 solid solution from 0 to
100%. It is noteworthy that ferroelectric phases can be realized without
primal ferroelectric material. This study creates an original solid
solution system with a rich spectrum of competing phases and demonstrates
an approach to design relaxor ferroelectrics for energy storage applications
and beyond.
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