A fluorinated acrylate copolymer emulsion with core-shell structure was synthesized by semi-continuous emulsion polymerization using methyl methacrylate (MMA ), butyl acrylate (BA) as the raw material, hexafluorobutyl methacrylate as fluorinated acrylate monomer, ammonium persulfate (APS) as initiator, sodium dodecyl sulfate (SDS) and polyoxyethylene octyl phenyl ether (OP-10) as emulsifier and taking water as dispersion medium. The as-prepared latexes are characterized by Fourier transforms infrared (FT-IR) spectroscopy. The hydro-oleophobic of copolymer is determined by contact angle meter. The typical core-shell structure is proved by differential scanning calorimetry (DSC). The results show that the copolymer emulsion has good hydro-oleophobic when the content of hexafluorobutyl methacrylate is 15%, used the delay loading method, the water contact angle of the coating surface is 104 °, the hexadecane contact angle is 75 °. Key words: fluorinated acrylate; copolymer; emulsion; hydro-oleophobic; contact angle

pH value of fluorescent ink-jet ink has an obvious influence on fluorescent powder, high or low pH value could cause some problems, such as fluorescence quenches, fluorescent quantum yield decreased, and so on. And these factors make against fluorescent ink-jet ink luminous properties reach the best result. This article is to design fluorescent ink-jet ink formula when it is exposured to deep Ultraviolet light to display green, and a series of ink samples were prepared. pH regulator was used to regulate pH value of green fluorescent ink-jet ink system. This paper discusses the effects of pH value on luminous intensity, fluorescent quantum yield. The results indicated that triethanolamine can regulate pH value of fluorescent ink-jet ink, when pH value increases from 8.70 to 11.20, luminous intensity, fluorescent quantum yield have a decrease tendency.