Selenium cathode has been demonstrated as a promising candidate of cathode material for low‐cost and high‐energy density potassium ion batteries (PIBs). Nevertheless, their applications are prevented by poor electrochemical performance due to the shuttle effect of high‐order polyselenides, the sluggish diffusion of bigger K+, and the huge volumetric expansion during cycling. In this work, we design a multifunctional Se host (N‐HCNS) by grafting ZIF‐8‐derived microporous carbon onto the surface of N‐doped porous carbon nanosheets. The obtained N‐HCNS carbon matrix integrates conductivity, captivity, and immobility abilities, which inhibits the polyselenides shuttle, improves the Se utilization, and buffers the volume change during cycling. The 3D hollow carbon skeleton enhances the infiltration of electrolytes. As an cathode for PIBs, the Se@N‐HCNS electrode delivers an unprecedented life‐span (260 mAh g−1 at 1.0 A g−1 after 2000 cycles) and exhibits a remarkable rate capacity (339 mAh g−1 at 5.0 A g−1). Density functional theory (DFT) calculation reveals the effective adsorption of K2Se with pyridine and pyrrole nitrogen doping in carbon matrix. The unique synergetic design of electrode not only gives insight into the reaction mechanism but also highly emphasizes the potential capabilities of N‐doped carbon in K‐Se batteries.
The corrosion inhibition and adsorption behavior of sodium alginate on AZ31 magnesium alloy in 3.5 wt% sodium chloride solution is investigated. The results show that sodium alginate can effectively inhibit the corrosion of AZ31 magnesium alloy. With increasing sodium alginate concentration, the inhibition efficiency initially increases and then decreases. It reaches a maximum of 90.00% at a sodium alginate concentration of 500 ppm. The inhibition is due to adsorption of sodium alginate on the bare magnesium alloy surface, where it mixes with magnesium hydroxide to form a more continuous and compact film, which retards the corrosion of the alloy.
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