The BSF reaction system displayed photoinduction and photoinhibition behavior under flow conditions. The oscillatory period decreased as the light irradiation mainly enhanced the negative process and affected the positive feedback.
Nonlinear chemical reactions produce
interesting chemohydrodynamic
patterns in an unstirred medium, which act as interesting demonstrations
to display the novel phenomena in a nonequilibrium chemical system.
Here, we report new outreach experiments: pH chemohydrodynamic patterns
modulated by sodium polyacrylate in the bromate–sulfite–ferrocyanide
(BSF) reaction system. In an unstirred Petri dish, transient pH stripe
patterns for a bromate–sulfite–ferrocyanide reaction
system driven by proton autocatalysis and isothermal density-induced
flow can be initiated in the center of approximately two-dimensional
Petri dishes by adding a small amount of sulfuric acid solution with
a certain concentration. Finally, the transient patterns are restored
to the homogeneous high pH state due to proton negative feedback.
The addition of sodium polyacrylate can not only lead to horizontal
Marangoni flow for forming filamentary pH patterns but also decreases
the diffusion of hydrogen ions, which results in a monotonic relationship
between the pattern lifetime and polyacrylate concentration. Through
these simple, lively and interesting experimental demonstrations,
undergraduate students majoring in chemistry can realize the effect
of transportations such as diffusion, density-induced flow, and Marangoni
flow on complex pattern formation driven by a simple inorganic clock
reaction.
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