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CO 2 hydrogenation to gasoline fuels remains a sticky problem of CO selectivity from reverse water-gas shift reactions over a metal oxide and zeolite bifunctional catalyst. Herein, we report an efficient catalyst combining a Fe−Zn−Zr−T oxide hydrothermally treated with TPABr solution and HZSM-5 zeolite for CO 2 hydrogenation into high-quality gasoline. The hydrothermal treatment contributes to the obvious enrichment of the Zn component and the residual Br on the surface of Fe−Zn− Zr−T oxide, as compared to Fe−Zn−Zr oxide, as well as the increased number of oxygen vacancies. These surface properties not only induce the increase of the H 2 adsorption and CO 2 adsorption ratio but also enhance the adsorption strength of the HCOO* species and the desorption rate of CH 3 O* species (close intermediate of methanol) over Fe−Zn−Zr−T oxide, which are responsible for higher methanol selectivity and lower CO selectivity. Furthermore, the presence of the adsorbed CO* species and higher C 2+ hydrocarbon selectivity on Fe−Zn−Zr oxide affirm the F−T route of CO 2 hydrogenation except for the methanol route, while the F−T route is effectively restrained after the TPABr hydrothermal treatment of Fe−Zn−Zr−T oxide. As the Fe and Zn−Zr molar ratio decreases, more HCOO* and CH 3 O* species on Fe−Zn−Zr (0.1:1:1)−T−24 h can form, which is in good agreement with the much higher methanol selectivity on Fe−Zn−Zr (0.1:1:1)−T−24 h oxide and hydrocarbon selectivity on the Fe−Zn− Zr(0.

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