The use of alternative fuels derived from residues in energy-intensive industries that rely on fossil fuels can cause considerable energy cost savings, but also significant environmental benefits by conserving non-renewable resources and reducing waste disposal. However, the switching from conventional to alternative fuels is challenging for industries, which require a sound understanding of the properties and combustion characteristics of the alternative fuel, in order to adequately adapt their industrial processes and equipment for its utilization. In this work, a solid recovered fuel (SRF) obtained from the polymeric fraction of an automotive shredder residue is tested for use as an alternative fuel for scrap preheating in an aluminium refinery. The material and chemical composition of the SRF has been extensively characterized using proximate and ultimate analyses, calorific values and thermal degradation studies. Considering the calorific value and the chlorine and mercury contents measured, the SRF can be designated as class code NCV 1; Cl 2; Hg 2 (EN ISO 21640:2021). The combustion of the SRF was studied in a laboratory-scale pilot plant, where the effects of temperature, flow, and an oxidizer were determined. The ash remaining after combustion, the collected liquid, and the generated gas phase were analysed in each test. It was observed that increasing the residence time of the gas at a high temperature allowed for a better combustion of the SRF. The oxidizer type was important for increasing the total combustion of the vapour compounds generated during the oxidation of the SRF and for avoiding uncontrolled combustion.
The end of fife (EoL) of new aircraft panels made of Al-Li alloys in which the stringers and skin were joined, either by laser beam welding (LBW) or by friction stir welding (FSW), was investigated at the lab scale. Different cutting strategies, ranging from cutting only for size reduction to full separation of all materials, including the removal of the welded seam, were defined, with the objective of recycling the maximum amount of panel scrap back into high-quality aircraft Al-Li alloys. Those welded aerostructures were coated with two novel Cr-free coating systems. The effect of the coatings on the recyclability of the panels and the need to eliminate the primer and topcoats were researched. Fading/enrichment of the alloying elements during recycling was determined. The chemical compatibility of the recycled alloys with four commercial Al-Li alloys was examined. The EoL route that maximized closed-loop recycling and the conservation of the valuable alloying elements was identified. Nine out of the ten configurations were found to be compatible with joint recycling. Only the LBW structure with ER4047 filler wire required sorting into scrap fractions and removing the weld seam. Decoating by corundum blasting followed by cutting before remelting is the recommended EoL process.
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