This microreview presents the use of 1,3-oxazolidines, prepared from enantiomerically pure β-amino alcohols, as chiral inductors for the stereoselective transformation of adjacent prostereogenic C=C or C=O bonds. After a brief chronological presentation of the major advances in this field, a convenient synthesis of N-Boc-2-acyl-and -2-alkenyloxazolidines is presented, together with the use of these heterocycles in asymmetric synthesis. The important role played by the Boc group on the nitrogen of the heterocycle in these trans-
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.