[1] Glacial millennial-scale paleoceanographic changes in the Southeast Pacific and the adjacent Southern Ocean are poorly known due to the scarcity of well-dated and high resolution sediment records. Here we present new surface water records from sediment core MD07-3128 recovered at 53°S off the Pacific entrance of the Strait of Magellan. The alkenone-derived sea surface temperature (SST) record reveals a very strong warming of ca. 8°C over the last Termination and substantial millennial-scale variability in the glacial section largely consistent with our planktonic foraminifera oxygen isotope (d 18 O) record of Neogloboquadrina pachyderma (sin.). The timing and structure of the Termination and some of the millennial-scale SST fluctuations are very similar to those observed in the well-dated SST record from ODP Site 1233 (41°S) and the temperature record from Drowning Maud Land Antarctic ice core supporting the hemispheric-wide Antarctic timing of SST changes. However, differences in our new SST record are also found including a long-term warming trend over Marine Isotope Stage (MIS) 3 followed by a cooling toward the Last Glacial Maximum (LGM). We suggest that these differences reflect regional cooling related to the proximal location of the southern Patagonian Ice Sheet and related meltwater supply at least during the LGM consistent with the fact that no longer SST cooling trend is observed in ODP Site 1233 or any SST Chilean record. This proximal ice sheet location is documented by generally higher contents of ice rafted debris (IRD) and tetra-unsaturated alkenones, and a slight trend toward lighter planktonic d18 O during late MIS 3 and MIS 2.
In six small catchments located at the Cordillera de la Costa in southern Chile (40°S), concentrations and fluxes of NO 3 -N, NH 4 -N, organic-N, total-N and total-P in bulk precipitation and runoff water were measured. The main objective of this study was to compare nitrogen and phosphorus retention of catchments with varying land cover of native forest and exotic plantations, in order to evaluate possible effects of land use change. Nitrate-N was the dominant fraction (>50%) of nitrogen loss, especially in the catchments dominated by exotic plantations. In the catchment with native forests, NO 3 − only contributed with 34% of the nitrogen loss and DON was the main output with 55%. Annual NO 3 − export was lower in the catchment with native forest compared to the catchments with exotic plantations where the streamflow output exceed the precipitation input. Average inputs of total-N were 2.6 kg ha −1 year −1 (DIN=1.4 kg ha −1 year −1 , DON=1.2 kg ha −1 year −1 ) and outputs were 1.7 kg ha −1 year −1 (DIN= 1.2 kg ha −1 year −1 , DON=0.5 kg ha −1 year −1 ). Annual retention of total nitrogen fluctuated between 61% in a catchment dominated by native forests to 15% in catchments dominated by exotic plantations of Eucalyptus sp. Nitrogen retention was positively related with native forest coverage. The N retention capacity of the catchments could be both attributed to consequences of clear cutting practices and differences in vegetation cover.
One of the most important factors controlling fjord primary production in southernmost Patagonia is the variability in the thermohaline structure of the water column. In the present-day environment, thermal stratification is mostly related to freshwater input and in particular, the seasonal melting of glaciers. Here we assess whether this relation between fjord productivity and freshwater input holds true for the Holocene, using a sediment record from the central basin of the Strait of Magellan (core MD07-3132, 53°44.17′S; 70°19.03′W, 301 m). Our approach relies on a proxy-based reconstruction of fjord sea surface temperature (alkenone SST), paleosalinity, freshwater input, and paleoproductivity. The results indicate that, during the early Holocene, the accumulation rate (AR) of marine organic carbon was low (b 20 kg m −2 kyr −1), most likely due to high freshwater contribution resulting in low salinity and low SSTs. After 8.5 kyr BP and during the mid and late Holocene all the productivity proxies increase. The AR's of marine organic carbon (~30 kg m −2 kyr ) reached the highest values during the last millennium. This increase was probably driven by the marine transgression where marine macronutrient-rich waters entered into the central basin, while lowered precipitation and decreased meltwater input contributed to increase the basin's SSTs and salinity. The late Holocene rise in productivity was interrupted by a low salinity phase between 3.2 and 2.2 kyr BP, during which productivity returned to early Holocene conditions in response to increased input of glacial clays, as suggested by high values of K/Si ratio (~1.2). Our results indicate that meltwater contribution from glaciers plays a crucial role in controlling fjord productivity on seasonal to millennial timescales.
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