A one-dimensional fluid simulation model of He/N2 dielectric barrier discharge with parallel plate electrodes was established to study the effects of different parameters (such as gap width, secondary electron emission coefficient γ, and driven frequency) on the characteristics of multiple current pulse (MCP) discharge and the discharge mode conversion. The discharge can be divided into Townsend discharge, transition state, and glow discharge. The results show that with the increase in γ, the number of discharge current pulses increases, making it more difficult to form a glow discharge. When γ is larger, the first discharge approaches the glow discharge mode, but the positive column region is not completely formed, and the subsequent discharge sequence undergoes a transition state to Townsend discharge gradually. Under the condition of larger γ, MCP discharge with a short gap is Townsend discharge. With the increase in the gap width, the transition state will appear in the first discharge, and the subsequent discharge sequence may be converted into Townsend discharge. When the gap width increases further, the discharge can be completely transformed into glow discharge. The pulse number of discharge current decreases with the increase in frequency, and the higher frequency is conducive to the formation of glow discharge.
On the basis of plasma technology, the progress of the volatile organic compounds' (VOCs') degradation by low‐temperature plasma alone is discussed first, including reactor types, influencing factors of plasma degradation of VOCs and the reaction mechanism between plasma and VOCs. Then, the research status of three VOC degradation technologies (catalysis, adsorption, and biotechnology) and their synergistic degradation of VOCs with plasma are reviewed, including the effect of catalyst position on VOC degradation, the interaction mechanism between plasma and catalyst; the factors affecting the adsorption of VOCs by carbon‐based adsorbents and zeolite, the degradation of VOCs by plasma‐assisted adsorbent; the features of different biological systems, the influencing factors of VOC degradation by the biotrickling system, and the degradation of VOCs by plasma‐assisted biotreatment. Finally, the prospects of developments in high‐tech based on plasma are discussed.
Outside Front Cover: Plasma technology has shown the important role in environment protection field and relative disciplines. We reviewed here the research progress of VOC degradation related to the plasma technology which benefits from the retrievable excellent researches. The degradation mechanism of VOCs when the plasma was introduced in reactions was discussed from different views. They are plasma alone, and plasma cooperating with the other technologies, such as catalyst, adsorbent, biotreatment, etc. Further details can be found in the article by Zhengshi Chang, Cong Wang, and Guanjun Zhang (https://doi.org/10.1002/ppap.201900131).
Inside Front Cover: CO2, which widely exists in Martian atmosphere, can be converted into O2 and fuel in‐situ. The in‐situ utilization of the abundant CO2 resources will support the construction of Mars energy base. The conversion method based on plasma technology is expected to activate and transform CO2 molecules under mild conditions. The oxygen can be used for astronauts to breathe and the fuel will be stored to power the launcher or lander as well as the many activities on Mars. Further details can be found in the article by Cong Wang, Qiang Fu, Zhengshi Chang, and Guanjun Zhang (https://doi.org/10.1002/ppap.202000228).
Mars has a special carbon dioxide environment. The surface and atmosphere of Mars contain a large amount of solid and gaseous carbon dioxide, which makes the in‐situ resource utilization of Martian carbon dioxide attract widespread attention. The conversion of carbon dioxide into fuel or high value‐added products through electrical discharge has become a research focus, in which numerical simulation is one of the important means to explain the experimental phenomenon and the mechanism. Therefore, a one‐dimensional fluid model was established in this paper to simulate the discharge and conversion of carbon dioxide under simulated Martian atmospheric pressure. The discharge mode, particle distribution, and discharge mechanism were studied by considering CO2 vibrational states and vibration relaxation reaction in the model. The results show that the discharge mode is glow discharge with an obvious cathode fall region, negative glow space, and positive column. The density of the four discharge products, C, O2, CO, and O, shows a step‐up trend, showing a significant cumulative effect, and the peak values appear near both electrodes. The density of vibrational states of CO2 molecule, which is highest in the neutral products, increases during the discharge stage and decreases after the discharge is extinguished. The temporal and spatial distribution of reaction rates shows that vibrational excitation, electronic excitation, and vibrational relaxation reactions dominate the loss and formation of CO2. The density of ground‐state CO2 decreases obviously in the discharge stage, and the minimum density appears near the instantaneous cathode. After the discharge is extinguished, the CO2 near the instantaneous cathode increases gradually.
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