A way to make cholesteric films reflecting in a broad wavelength band consists in associating different cholesteric pitches in the same film. In two previous papers, we proposed an efficient method to produce variable pitch films, based on a thermal processing, and we studied the optical properties of these films with respect to the time of processing. In the present paper, we study the microstructure of such films with respect to the processing time by means of transmission electron microscopy. The cholesteric phase is shown to be very well ordered. Within a wide range of annealing times, its periodicity is progressive from one face to the other of the film. A description of the evolution of the structure with respect to the processing time is given, and classified in three stages, corresponding to the three stages already stated from the optical properties. The relationship between the evolution of the structure and the optical properties is discussed.
PACS. 61.30.Eb Experimental determinations of smectic, nematic, cholesteric, and other structures -61.30.-v Liquid crystals -61.16.Bg Transmission, reflection and scanning electron microscopy (including EBIC)
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The reflection properties of cholesteric films with thermally induced pitch gradients are theoretically and experimentally studied. It is shown that the optical behavior of such films corresponds to the averaged contribution of a number of stochastic pitch variation profiles, due to the transversal and longitudinal nonuniformities that develop in the helical structure of such samples. Depending on the annealing time, both narrow-band and broadband behavior can be selectively achieved. The influence of the pitch profile gradient on the broadband reflection performance of cholesteric samples is theoretically analyzed, and a multi-slab structure for achieving optimum efficiency is proposed.
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