*a quien debe dirigirse la correspondencia RESUMEN el comportamiento de diferentes modelos de isotermas de adsorción aplicados a los datos experimentales obtenidos por Gasparik et al. (2012) en una prueba de adsorción de metano, fue modelado y analizado, con el fi n de determinar el que mejor representa los datos experimentales. entre los modelos utilizados se encuentran algunos de dos parámetros como Langmuir, temkin y freundlich, otros de tres parámetros como Langmuir, DubininRadushkevich, Toth y Sips; de cuatro parámetros como Dubinin-Astakhov y Fritz-Schlunder y fi nalmente el modelo de cinco parámetros propuesto por fritz-schlunder. según los resultados obtenidos, los modelos presentaron mejor ajuste a medida que empleaban mayor número de parámetros en sus ecuaciones.Posteriormente se calculó la capacidad de almacenamiento total de gas para una formación hipotética con algunos datos de la formación Posidonea empleando el método propuesto por Ambrose et al (2010), el cual se modifi có reemplazando el término que tiene en cuenta el gas adsorbido con los modelos mencionados anteriormente, a fi n de determinar su infl uencia en las estimaciones de volumen de gas libre y de gas adsorbido. Con los modelos que presentaron un menor porcentaje de error, se obtuvieron datos más conservadores en el cálculo del gas adsorbido y de gas total, lo cual indica la importancia de la adecuada selección del modelo para el cálculo de reservas, dado que conlleva alto impacto técnico y económico.Palabras clave: shale, gas, yacimiento, isotermas, adsorción. Application of adsorption isotherm models of methane on a shale sample and their impact on reserves estimation ABSTRACTSeveral adsorption isotherm models were analyzed for the purpose of fi tting the experimental data published by Gasparik et al. (2012) obtained in a methane adsorption experiment on a shale sample from the Posidonea formation in the netherlands. the following are the ten models used in this study; some of them consist of two parameters such as Langmuir, temkin and freundlich, the three parameter models: Langmuir, DubininRadushkevich, Toth and Sips, four parameters: Dubinin-Astakhov and Fritz-Schlunder and the fi ve-parameter Fritz Schlunder correlation. The results show a better fi t to the experimental data for those models with the highest number of parameters.
Accuracy of earthquake location methods is dependent upon the quality of input data. In the real world, several sources of uncertainty, such as incorrect velocity models, low Signal to Noise Ratio (SNR), and poor coverage, affect the solution. Furthermore, some complex seismic signals exist without distinguishable phases for which conventional location methods are not applicable. In this work, we conducted a sensitivity analysis of Back-Projection Imaging (BPI), which is a technique suitable for location of conventional seismicity, induced seismicity, and tremor-like signals. We performed a study where synthetic data is modelled as fixed spectrum explosive sources. The purpose of using such simplified signals is to fully understand the mechanics of the location method in controlled scenarios, where each parameter can be freely perturbed to ensure that their individual effects are shown separately on the outcome. The results suggest the need for data conditioning such as noise removal to improve image resolution and minimize artifacts. Processing lower frequency signal increases stability, while higher frequencies improve accuracy. In addition, a good azimuthal coverage reduces the spatial location error of seismic events, where, according to our findings, depth is the most sensitive spatial coordinate to velocity and geometry changes.
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