The aim of this study was twofold. Firstly, we performed a land capability class determination of the agricultural soils from the Abu Dhabi Emirate, the United Arab Emirates, based on the concentrations of 17 chemical elements determined in the soil samples collected from 84 locations. Secondly, we assess the soil pollution with different metals, using several pollution indices. The results of Principal Component Analysis (PCA) shows that four principal components (PCs) are responsible for describing the total metals concentrations’ variance, the highest contribution on PC1 being that of Mn, and Cr, on PC2 that of Fe, on PC3 that of Cu, and on PC4 that of Al. After determining the optimal number of clusters, we classified the sites into three clusters, while the studied metals were grouped function on their concentrations. Then, we used five indices to assess the pollution level of the soil at the study sites and in the clusters. The geo—accumulation index (Igeo) indicates uncontamination/moderately contamination with Cu in cluster 1, uncontaminated/moderately contaminate soils with Cd, Cu, and Ni in cluster 2, and uncontaminated/moderately contaminated soil with Cu and moderately contaminated with Pb, Zn, and Ni in cluster 3. By comparison, the enrichment factors overestimate the pollution of the studied sites. The pollution load index (PLI) indicates a baseline level of pollution at 14 sites and the deterioration of the soil quality at four sites. The Nemerow pollution index provides similar results as PLI.
The Liwa area is a primary food production area in the United Arab Emirates (UAE) and has intensively been used for agriculture. This study investigates the pollution levels with heavy metals in agricultural soils from the Liwa area. Thirty-two soil samples were analyzed for Mn, Zn, Cr, Ni, Cu, Pb, Cd, Co, and As. Results revealed that heavy metal levels varied in the ranges 220.02–311.21, 42.39–66.92, 43.43–71.55, 32.86–52.12, 10.29–21.70, 2.83–8.84, 0.46–0.69, 0.03–0.37 mg/kg for Mn, Zn, Cr, Ni, Cu, Pb, Cd, Co, and As, respectively. All samples presented low As concentrations with an average of 0.01 mg/kg. The variations in bulk metal contents in the soil samples were related to multiple sources, including agrochemicals, atmospheric dust containing heavy metals, and traffic-related metals. Enrichment factor analysis indicates that Cd, Ni, Zn, and Cr were highly enriched in soils, and they could originate from non-crustal sources. Based on the geo-accumulation index (Igeo), the soil samples appeared uncontaminated with Mn, Cr, Zn, Pb, Co, As, Cu, uncontaminated to moderately contaminated with Ni and moderately contaminated with Cd. The contamination factors suggest low contamination, except for Ni, which showed moderate contamination. The average pollution load index (PLI) revealed unpolluted to low pollution of all soil samples. The ecological risk assessment (PERI) showed that all heavy metals posed a low risk, except for Cd which exhibited a high ecological risk.
This study aims at providing bee products and derivatives of medicinal plant consumers with a multifaceted perspective on mineral elements occurring in the soils of two forest zones in the vicinity of North Dobrogea (Romania) by (1) analyzing the pollution levels of the soils at three sites (denoted by DS, PH, and ST) in the study region, using different indicators; (2) providing the results of the transfer of metals from the soil to Sambucus nigra L. (SnL), Hypericum perforatum (Hp), and Tilia tomentosa (Tt). The statistical analysis of the series collected at these locations shows no difference between the elements’ concentrations (as a whole). Still, the values of the geo-accumulation index (Igeo) classify the soils as being soils that are moderately to highly contaminated with Cd (and not contaminated with Cu, Mn, or Zn) with respect to the European background values. The cumulative indices—the degree of contamination (DC), the pollution load index (PLI), the Nemerow integrated pollution index (NIPI), and the potential ecological risk index (PERI) indicated the highest contamination in DS (which is a tourist area). To assess the accumulation of different metals in plants, the enrichment factors (EF) were computed. In over 75% of cases, EF was above 1, indicating a high degree of enrichment with different metals. The highest values were those for Cu (41.10 in DS for SnL), and Cd (12.85 in DS for Tt). The results showed that there were different degrees of accumulation between microelements and trace elements in the plants. Tt acted as a bioaccumulator for almost all of the studied elements (K, Mg, Na, Fe, Mn, Cu, Zn, and Cd).
Dust is a significant pollution source in the United Arab Emirates (UAE) that impacts population health. Therefore, the present study aims to determine the concentration of heavy metals (Cd, Pb, Cr, Cu, Ni, and Zn) in the air in the Sharjah and Ajman emirates’ urban areas and assesses the health risk. Three indicators were used for this purpose: the average daily dose (ADD), the hazard quotient (HQ), and the health index (HI). Data were collected during the period April–August 2020. Moreover, the observation sites were clustered based on the pollutants’ concentration, given that the greater the heavy metal concentration is, the greater is the risk for the population health. The most abundant heavy metal found in the atmosphere was Zn, with a mean concentration of 160.30 mg/kg, the concentrations of other metals being in the following order: Ni > Cr > Cu > Pb > Cd. The mean concentrations of Cd, Pb, and Cr were within the range of background values, while those of Cu, Ni, and Zn were higher than the background values, indicating anthropogenic pollution. For adults, the mean ADD values of heavy metals decreased from Zn to Cd (Zn > Ni > Cr > Cu > Pb > Cd). The HQ (HI) suggested an acceptable (negligible) level of non-carcinogenic harmful health risk to residents’ health. The sites were grouped in three clusters, one of them containing a single location, where the highest concentrations of heavy metals were found.
Gold is one of the precious metals with multiple uses, whose deposits are much smaller than the global production needs. Therefore, extracting maximum gold quantities from industrial diluted solutions is a must. Am-L-GA is a new material, obtained by an Amberlite XAD7-type commercial resin, functionalized through saturation with L-glutamic acid, whose adsorption capacity has been proved to be higher than those of other materials utilized for gold adsorption. In this context, this article presents the results of a factorial design experiment for optimizing the gold recovery from residual solutions resulting from the electronics industry using Am-L-GA. Firstly, the material was characterized using atomic force microscopy (AFM), to emphasize the material’s characteristics, essential for the adsorption quality. Then, the study showed that among the parameters taken into account in the analysis (pH, temperature, initial gold concentration, and contact time), the initial gold concentration in the solution plays a determinant role in the removal process and the contact time has a slightly positive effect, whereas the pH and temperature do not influence the adsorption capacity. The maximum adsorption capacity of 29.27 mg/L was obtained by optimizing the adsorption process, with the control factors having the following values: contact time ~106 min, initial Au(III) concentration of ~164 mg/L, pH = 4, and temperature of 25 °C. It is highlighted that the factorial design method is an excellent instrument to determine the effects of different factors influencing the adsorption process. The method can be applied for any adsorption process if it is necessary to reduce the number of experiments, to diminish the resources or time consumption, or for expanding the investigation domain above the experimental limits.
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