Despite the apparent stability of the electricity system from a consumer’s point of view, there is indeed significant effort exerted by network operators to guarantee the constancy of the electricity supply in order to meet demands any time. In the energy sector models provide an important conceptual framework to generate a range of insight, examine the impacts of different scenarios and analyze the supply and demand of energy. This paper presents a user-oriented and transparent modeling concept of the European calculator, a tool for delineating emission and sustainable transformation pathways at European and member state levels. The model consists of several modules of different sectors, where the energy supply module includes sub-modules for electricity generation, hydrogen production and oil refinery. The energy storage requirement module investigates how new technologies can help the stability of the European electricity system with increasing renewables penetration, demand-side measures and decarbonization paths. The objective of this study is to introduce the concept of this module with the main logical steps, especially the input parameters, assumptions, the basic data of electricity trade and maximum energy storage potential levels. The article also introduces and explains the feasibility of the theoretical maximum gross electricity generation potential from variable renewable energy for the European Union including Switzerland, compared to the demand in 2040. According to the results the electricity systems in the future will need to show ever increasing flexibility in order to cope with variable renewable energy production on the supply side, and shifting patterns of electricity consumption on the demand side.

One of the challenges of the present century is to limit the greenhouse gas emissions for the mitigation of climate change which is possible for example by a transitional technology, CO2 geological storage. Clay minerals are considered to be responsible for the low permeability and sealing capacity of caprocks sealing off stored CO2. However, their reactions are not well understood for complex simulations. This work aims to create a kinetic geochemical model of Na-montmorillonite standard SWy-2 supported by solution and mineral composition results from batch experiments. Such experimentally validated numerical models are scarce. Four 70-hours experiments have been carried out at atmospheric conditions, and with CO2 supercritical phase at 100 bar and 80 °C. Solution samples have been taken during and after experiments and their compositions were measured by ICP-OES. The treated solid phase has been analyzed by XRD and ATR-FTIR and compared to in-parallel measured references (dried SWy-2). Kinetic geochemical modelling of the experimental conditions has been performed by software PHREEQC. Experiments and models show fast reactions under the studied conditions and increased reactivity in presence of scCO2. Solution composition results cannot be described by the change of the uncertain reactive surface area of mineral phases. By considering the clay standard’s cation exchange capacity divided proportionally among interlayer cations of Na-montmorillonite, the measured variation can be described on an order of magnitude level. It is furthermore indicated that not only the interlayer cations take part in this process but a minor proportion of other, structural ions as well, differently in the reference and scCO2 environments.