Harvesting micro-droplets from fog is a promising method for solving global freshwater crisis. Different types of fog collectors have been extensively reported during the last decade. The improvement of fog collection can be attributed to the immediate transportation of harvested water, the effective regeneration of the fog gathering surface, etc. Through learning from the nature's strategy for water preservation, the hydrophobic/hydrophilic cooperative Janus system that achieved reinforced fog collection ability is reported here. Directional delivery of the surface water, decreased re-evaporation rate of the harvested water, and thinner boundary layer of the collecting surface contribute to the enhancement of collection efficiency. Further designed cylinder Janus collector can facilely achieve a continuous process of efficient collection, directional transportation, and spontaneous preservation of fog water. This Janus fog harvesting system should improve the understanding of micro-droplet collection system and offer ideas to solve water resource crisis.
Here, a smart fluid-controlled surface is designed, via the rational integration of the unique properties of three natural examples, i.e., the unidirectional wetting behaviors of butterfly's wing, liquid-infused "slippery" surface of the pitcher plant, and the motile microcilia of micro-organisms. Anisotropic wettability, lubricated surfaces, and magnetoresponsive microstructures are assembled into one unified system. The as-prepared surface covered by tilted microcilia achieves significant unidirectional droplet adhesion and sliding. Regulating by external magnet field, the directionality of ferromagnetic microcilia can be synergistically switched, which facilitates a continuous and omnidirectional-controllable water delivery. This work opens an avenue for applications of anisotropic wetting surfaces, such as complex-flow distribution and liquid delivery, and extend the design approach of multi-bioinspiration integration.
Biosurfaces with geometry-gradient structures or special wettabilities demonstrate intriguing performance in manipulating the behaviors of versatile fluids. By mimicking natural species, that is, the cactus spine with a shape-gradient morphology and the Picher plant with a lubricated inner surface, we have successfully prepared an asymmetric slippery surface by following the processes of CO-laser cutting, superhydrophobic modification, and the fluorinert infusion. The asymmetric morphology will cause the deformation of gas bubbles and subsequently engender an asymmetric driven force on them. Due to the infusion of fluorinert, which has a low surface energy (∼16 mN/m, 25 °C) and an easy fluidic property (∼0.75 cP, 25 °C), the slippery surface demonstrates high adhesive force (∼300 μN) but low friction force on the gas bubbles. Under the cooperation of the asymmetric morphology and fluorinert infused surface, the fabricated asymmetric slippery surface is applicable to the directional and continuous bubble delivery in an aqueous environment. More importantly, due to the hard-compressed property of fluorinert, the asymmetric slippery surface is facilitated with distinguished bubble transport capability even in a pressurized environment (∼0.65 MPa), showing its feasibility in practical industrial production. In addition, asymmetric slippery surfaces with a snowflake-like structure and a star-shaped structure were successfully fabricated for the real-world applications, both of which illustrated reliable performances in the continuous generation, directional transportation, and efficient collection of CO and H microbubbles.
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