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Currently there are no international standards for evaluating the tracking and erosion resistance of DC polymeric insulation under contaminated conditions. Researchers often modify the existing AC inclined plane test standards such as the IEC-60587 to accommodate DC voltage conditions but this has been reported to give various inconsistences. This paper presents comprehensive experimental results on inclined plane tests of silicone rubber (SiR) insulation at 3.5 and 4.5 kV AC and positive DC using intravenous (IV) system as the pollutant supply. The leakage currents (LC) were recorded throughout the entire tests. In addition, various physiochemical tests namely, Fourier Transform Infrared analysis, thermo-gravimetric analysis, scanning electron microscopy and energy dispersive spectroscopy were performed on the aged and unaged samples. Results show that DC LC is bigger (about three times) than that under AC for the same equivalent voltages. Furthermore, DC LC variations are less random and the average magnitudes increase with duration of voltage application compared with AC. The physiochemical analyses show that 3.5 kV rms AC and 3.5 kV DC aged samples have comparable chemical characteristics albeit with electrode corrosion elements detected on the DC aged samples. Under 4.5 kV DC the degradation becomes significantly more severe and unrepeatable. It is therefore concluded that at 0.3 ml/min, pollutant flow rate, 3.5 kV positive DC and 3.5 kV rms AC are comparable as test voltages for inclined plane accelerated ageing of SiR insulation.

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Thermal stress and moisture absorption can cause a synergetic negative impact on kraft paper. Among various approaches for improving the dielectric properties of kraft paper, nanotechnology has had promising results. However, the hydrophilicity of most metal oxide nanoparticles renders nanomodified kraft paper more vulnerable to thermal stress and moisture, thereby inducing degradation. In nanomodified kraft paper research, the use of TiO2 nanoparticles has yielded the most promising results. The major shortfall, however, is the hydrophilicity of TiO2. This work investigated surface modifications of rutile-TiO2 nanoparticles (NPs) for improved hydrophobicity and thermal stability. Rutile-TiO2 NPs is a nontoxic metal oxide that can withstand high temperature and is stable in chemical reactions. Two cases of surfactants were used—alkyl ketene dimer (AKD) and alkenyl succinic anhydride (ASA). The intention was to increase heat resistance and reduce the surface free energy of the rutile-TiO2 NPs. The impacts of the surface modifiers on the rutile-TiO2 NPs were characterised using FT-IR, muffle furnace, analytical weight balance, and TGA. It was discovered that new functional groups were formed on the modified NPs examined through FT-IR spectra. This indicates new chemical bonds, introduced through the surface modification. The unmodified rutile-TiO2 NPs absorbed moisture, increasing their mass by 3.88%, compared with the modified nanoparticles, which released moisture instead. TGA analysis revealed that AKD- and ASA-modified rutile-TiO2 needed higher temperatures than the unmodified rutile-TiO2 to markedly decompose. AKD, however, gave better performance than ASA in that regard. As an example, those modified with 5% AKD sustained a 45% higher temperature than the pure TiO2 nanoparticles. Furthermore, in both cases of the surfactants, the higher the percent of surfactant content was, the more thermally stable the nanoparticles became. This work demonstrates the possibility of fabricating rutile-TiO2 NPs to give improved hydrophobicity and thermal stability for possible dielectric applications such as in kraft paper for power transformer insulation.

The supply voltage frequency effect on partial discharge (PD) phenomena has continued to draw research interest. Although most high voltage equipment operates at power frequency (50/60 Hz), testing is often done at different frequencies for various reasons. Despite some agreements and inconsistencies for the research findings of PD activity’s frequency dependence, there has been consensus on the recognition of the discharge mechanism parameters that influence how the supply voltage frequency affects PD activity. These parameters include statistical time lag, discharge area surface conductivity, and the residual charge decay. In this paper, a 3-capacitor model (ABC) is used to simulate how the changes in the discharge mechanism parameters influence PD characteristics as a function of the supply voltage frequency. The findings are that the phase-resolved partial discharge pattern (PRPDP) and PD repetition rate (PDRR) characteristics are more sensitive to variations in the probability of the seed electron availability at higher frequencies of the supply voltage. The opposite trend is observed for the cavity surface resistance. At lower resistance of cavity surface, the PRPDP and PDRR characteristics are more sensitive to changes in the supply voltage frequency than at higher resistances. The paper also confirms that incorporating equivalent resistances in the ABC model makes it more authentic than the model comprising of capacitors only.