AbsbzcfThe coplanar-grid charge sensing technique provides a method for improving the spectral response of gamma-ray detectors based on compound semiconductors, which typically have poor charge transport properties. The technique functions by effectively modifying the charge induction characteristics cf the detector such that the dependence of detector signal on 'the depth of radiation interaction is minimized. The effdveness of this technique however can be compromised by non-uniform charge induction characteristics across the detector. This paper examines such non-uniformity due to fringe effects near the detector edges. Alternate electrode ~onfi~gwations are studied that provide effective compensation for such effects. Results fiom experimental measurements and computer simulations are presented.
the size of the ortho-alkyl substituents parallels changes in other constants derived from the same structural differences, as may be seen from the data in Table IV. Again, only limited comparable data are available.As to the application of the HFA technique to quantitative analysis, it can be concluded that although it is applicable to most phenols, caution should be exercised in systems where there is a bulky ortho substituent or a strong electronegative group at the meta or para position. In such systems, the equilibrium does not lie too far to the right. This, however, can be partially overcome by the presence of a great excess of free HFA. For example, to reach 99% reaction in a substituted phenol whose K with HFA is 100, a 1.0 molar excess of HFA should be present.
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