The work considers direct and indirect electrochemical methods of activation of hydrogen sulfide in the reaction with cycloheptane. It is suggested to apply anodic (cathodic) activation and combined redox systems including the electrode and chemical substance (oxidant, mediator, and deprotonating agent) to enhance H 2 S reactivity. It is shown that interaction between activated H 2 S with cycloheptane results in the product of thiolation of the substrate and the further formation of dicycloheptyl sulfide, dicycloheptyl disul fide, dicycloheptyl trisulfide, and dicycloheptyl sulfoxide. The current efficiency of sulfur-containing com pounds depends on the method of reagent activation and duration of the reaction.

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