Electron microprobe mineral composition data are presented for samples of exsolved and recrystallized garnet websterites within the mantle-derived peridotite bodies and of external orthopyroxene eclogite lenses directly enclosed within the gneisses on the islands of Fjørtoft and Otrøy in the Western Gneiss Region of Norway. These data are utilized to obtain P-T estimates that lie within the coesite stability field, and are mostly also compatible with rare observations of microdiamond formation and preservation for the deformed and re-equilibrated garnet websterite assemblages in the peridotite bodies included within the basement gneiss sequences on both islands. Equivalent P-T estimates for external orthopyroxene eclogite lenses within the basement gneisses on both islands are mostly not well constrained due to fairly extensive modification of orthopyroxene compositions during amphibolite-facies retrogression. Nonetheless, P-T estimates for the least retrogressed samples again indicate the likelihood that these rocks underwent Scandian ultrahigh-pressure metamorphism.We thus conclude that, contrary to a previously published interpretation, both the Caledonian Blåhø nappe sequence and the underlying Proterozoic Baltica basement gneisses on Fjørtoft experienced Scandian ultrahigh-pressure metamorphism, thus denying a previous suggestion that a major, greater than normal continental crust thickness, tectonic break exists between these rock sequences on this island. Similarly, the Baltica basement gneiss sequence exposed on the northern side of Otrøy, with its comparable mantle-derived peridotite bodies and external orthopyroxene eclogite lenses, is also shown to have been subjected to the Scandian ultrahigh-pressure metamorphic event.
The postulated difference in W isotopic composition of the Earth's core of $2 e W units, compared to the bulk silicate earth (BSE) has previously been used to search for evidence of core-mantle interaction (CMI) in ocean island basalts (OIB). The absence of W isotope anomalies has thus been taken as evidence that CMI does not occur. However, the addition of subducted sediment with high W to the sources of OIB could obscure a core signature. This possibility brings into question the utility of W isotopes as tracers for CMI. To accurately consider the effects of sediment addition to mantle sources of OIB with respect to W requires improved constraints on the abundances of W in subducting sediment. Here, we present high-precision W abundance data (and other HFSE) for a suite of sediments from the Banda subduction regime in East Indonesia. Subducting East Indonesian sediments have trace element concentrations that resemble those of average upper continental crust (UCC), making these sediments valuable to consider as typical of subducted sediments. Average W abundances of 2.1 ppm, corrected for carbon content coupled with current models of 0.5% core addition and 1% sediment addition to EM1 or HIMU plume, suggest that a model hybrid source should exhibit values of e W = À0.24 with $25 ppb W. Prior studies have not reported such low W isotopic compositions or high estimated W concentrations present in the sources of either Hawaiian or French Polynesian lavas, so such large additions of core material to these plume sources seems unlikely. Given these constraints, core contributions to these source, if present, can be no more than $0.1%.
As a step towards resolving the genesis of inclusions in diamonds, a new technique is presented. This technique combines cathodoluminescence (CL) and electron backscatter diffraction (EBSD) using a focused ion beamscanning electron microscope (FIB-SEM) instrument with the aim of determining, in detail, the three-dimensional diamond zonation adjacent to a diamond inclusion. EBSD reveals that mineral inclusions in a single diamond have similar crystallographic orientations to the host, within ±0.4°. The chromite inclusions record a systematic change in Mg# and Cr# from core to the rim of the diamond that corresponds with a *80°C decrease of their formation temperature as established by zinc thermometry. A chromite inclusion, positioned adjacent to a boundary between two major diamond growth zones, is multi-faceted with preferred octahedral and cubic faces. The chromite is surrounded by a volume of non-luminescent diamond (CL halo) that partially obscures any diamond growth structures. The CL halo has apparent crystallographic morphology with symmetrically oriented pointed features. The CL halo is enriched in *200 ppm Cr and *80 ppm Fe and is interpreted to have a secondary origin as it overprints a major primary diamond growth structure. The diamond zonation adjacent to the chromite is complex and records both syngenetic and protogenetic features based on current inclusion entrapment models. In this specific case, a syngenetic origin is favoured with the complex form of the inclusion and growth layers indicating changes of growth rates at the diamond-chromite interface. Combined EBSD and 3D-CL imaging appears an extremely useful tool in resolving the ongoing discussion about the timing of inclusion growth and the significance of diamond inclusion studies.
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