Magnetic-field-induced phase transitions are investigated in the frustrated gapped quantum paramagnet Rb2Cu2Mo3O12 through dielectric and calorimetric measurements on single crystal samples. It is clarified that the previously reported dielectric anomaly at 8 K in powder samples is not due to a chiral spin liquid state as has been suggested, but rather to a tiny amount of a ferroelectric impurity phase. Two field-induced quantum phase transitions between paraelectric/paramagnetic and ferroelectric/magnetically ordered states are clearly observed. It is shown that the electric polarization is a secondary order parameter at the lower-field (gap closure) quantum critical point, but a primary one at the saturation transition. Having clearly identified the magnetic BEC nature of the latter, we use the dielectric channel to directly measure the critical divergence of BEC susceptibility. The observed power-law behavior is in very good agreement with theoretical expectations for three dimensional BEC. Finally, dielectric data reveal new magnetic presaturation phases in this compound that may feature exotic order with unconventional broken symmetries.
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