Friction and wear of sintered alumina with grain sizes between 0.4 and 3 μm were measured in comparison with Al2O3/TiC composites and with tetragonal ZrO2(3 mol% Y2O3). The dependence on the grain boundary toughness and residual microstresses is investigated, and a hierarchical order of influencing parameters is observed. In air, reduced alumina grain sizes improve the micromechanical stability of the grain boundaries and the hardness, and reduced wear is governed by microplastic deformation, with few pullout events. Humidity and water slightly reduce the friction of all of the investigated ceramics. In water, this effect reduces the wear of coarser alumina microstructures. The wear of aluminas and of the Al2O3/TiC composite is similar; it is lower than observed in zirconia, where extended surface cracking occurs at grain sizes as small as 0.3 μm.
The tribological behaviour of different ceramics in contact with steel was studied for the case of oscillating sliding motion with a ball‐on‐disc apparatus. The influence of several test condition parameters was investigated by a systematic variation of the stroke, frequency, and normal load at room temperature in laboratory air at different levels of relative humidity. Each of the four parameters was varied in three stages. While the coefficient of friction was only mildly influenced by the operational variables, the coefficient of wear showed great variations and depended strongly on the humidity of the surrounding air. The effect of the operational variables and of the humidity on friction and wear varied for the different materials under investigation.
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