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Based on the example of a nanopowder system ZrO 2-3% mol Y 2 O 3 with atmospheric humidity interaction, the possibility of exothermic heterophase electrochemical energy conversion to electric energy is shown. Electrical properties and structure of the experimental sample were studied under gradient molecular flux density of humidity during sample saturation. The idea of development of the novel chemo-electronic converter device based on nanoscale dielectrics as ZrO 2-3% mol Y 2 O 3 is proposed.

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