The common notion suggests that metallic glasses (MGs) are a homogeneous solid at the macroscopic scale; however, recent experiments and simulations indicate that MGs contain nano-scale elastic heterogeneities. Despite the fundamental importance of these findings, a quantitative understanding is still lacking for the local elastic heterogeneities intrinsic to MGs. On the basis of Eshelby's theory, here we develop a micromechanical model that correlates the properties of the local elastic heterogeneities, being very difficult to measure experimentally, to the measurable overall elastic properties of MGs, such as shear/bulk modulus and Poisson's ratio. Our theoretical modeling is verified by the experimental data obtained from various MGs annealed to different degrees. Particularly, we revealed that the decrease of Poisson's ratio upon annealing of MGs is associated with a much large shear softening over hydrostatic-pressure softening, and vice versa in local elastic inhomogeneities. The relative extent of the bulk versus shear modulus softens is extracted for different MGs, and is found to closely depend on the specific composition and their ductility. The implication of our results on the Poisson's ratio criterion on the ductility as well as the aging dynamics in MGs is discussed.

In order to obtain the high conductivity values and wide spinel stability region for solid oxide fuel cell interconnect, several multilayer Ni, Co and Mn coatings are electroplated and then oxidized in air to form spinel oxide layers. Potentiodynamic polarization curves in different simple solutions are tested to analyze the deposition behavior of Co and Mn. Microstructures and compositions of Ni-Co-Mn multi-layers by adjusting the thickness and deposition parameters are analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that area specific resistance value of sample B-Ni/Co after oxidation at 750℃ for 500h is the lowest among the coatings, and the resistance values at 700℃ and 800℃ are 35.3 and 31.7 mΩ‧cm 2 , respectively. When the Ni transition layer in the vicinity of coating/substrate interface is thick, it will lead to the outward diffusion and aggregation of element Fe to form Fe-rich oxide intermediate layer, which will affect the high-temperature performance of the coating. Pure Co and CoMn alloy coatings with a certain thickness can effectively prevent the inward diffusion of oxygen and the outward diffusion of Fe and Cr at high temperature. The thin Ni transition layer combined with the thick Co layer or CoMn layer has the best element diffusion inhibition and high temperature electrical properties during the long-term high-temperature oxidation process.

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