The use of consequent p ro ced u res in d e sig n in g programming systems and languages fo r r e a l tim e, o n-lin e or m ultiprogram m ing a p p lic a tio n s is d is c u s s e d. Consequent procedures d i f f e r from normal procedures in th a t the flow o f c o n tr o l Detween p ro ced u res
AuszugDie Strukturen der drei isomorphen Verbindungen wurden nach der Methode der Ausgleichsrechnung verfeinert. Alle schweren Atome befinden sich in Punktlagen der Raumgruppe P63/m; es ist anzunehmen, daß auch die WasserstoffLagen dieser Raumgruppe entsprechen. Die Punktsymmetrie der Metallionen ist C 3h . Diese Ionen haben neun Waesermoleküle zu nächsten Nachbarn; sechs davon bilden die Ecken eines trigonalen Prismas und liegen zu dreien ober-und unterhalb der Spiegelungsebene, in der sich die übrigen drei Wassermoleküle und das Metallion befinden. Die sechs Er-O-Abstände vom Erbiumion zu den Prismenecken betragen 2,37 Ä, die Er-O-Abstände in der Spiegelungsebene sind 2,52 Ä. Die Symmetrie der nächsten Umgebung der Metallionen ist nahezu Ζ>3Λ. Achtzehn Sulfat-Ionen umgeben das Erbiumion in Abständen von 4,61 bis 4,77 Ä. Die Symmetrie der Umgebung der Metallionen ist nicht abhängig von deren Größe und auch nicht davon, ob es sich um eine Seltene Erde gerader oder ungerader Ordnungszahl handelt. Die Struktur des Äthylsulfations und die möglichen Wasserstoffbindungen werden diskutiert.
AbstractStructures of the three isomorphous compounds have been refined by leastsquares methods, the praseodymium compound in only two dimensions, the others in three dimensions. All heavy atoms are found in the space group P63jm, and there is reason to believe that hydrogen positions also conform to this space group. The point symmetry at the metal ion is, then, C 3h . The metal ion has nine water molecules as nearest neighbors; six form a trigonal.prism above and below the mirror plane containing the other three water oxygens and the metal Crystal structure of hydrated ethylsulfates 363 ion. The six Er-Ο distances to the prism are 2.37 A, and the remaining three are 2.52 A. If all but nearest oxygen positions are neglected, the symmetry about the metal ion is almost D3h. Eighteen sulfate oxygens are next-nearest neighbors of the metal ion at distances from 4.61 A to 4.77 A in the Er compound. The ethyl groups pack together about the origin of the unit cell. There is no detectable change in symmetry about the rare-earth ion with size or with odd and even numbers of electrons. The structure of the ethyl-sulfate ion and the possible hydrogen-bond positions are also discussed.The hydrated rare-earth ethylsulfates, M(C 2 H s S0 4 ) 3 · ΘΗ^Ο are of current international interest because of the investigation of crystal-field effects on the electronic and magnetic structure of the 4/-subshell 1-5 . One of the requirements for the interpretation of this work is an accurate knowledge of the local field symmetry about the rare-earth ion. In addition, if a calculation of the field parameters is to be attempted, accurate positions for the -various ions and the orientations of the water dipoles must be known. Of interest is the possible change in symmetry at the rare-earth ion with changes in size and electronic configuration of that ion.The structures of the rare-earth ethylsulfates have been studied by KETELAAR 6 who determined the lattice co...
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.